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Two different molecules have the formula \(\mathrm{C}_{2} \mathrm{H}_{2} \mathrm{Cl}_{2}\). Draw a Lewis structure for each molecule. (All the \(\mathrm{H}\) and \(\mathrm{Cl}\) atoms are bonded to carbon. The two carbon atoms are bonded to each other.)

Short Answer

Expert verified
The two possible Lewis structures for the given molecular formula are: 1. In the first structure, a hydrogen atom and a chlorine atom are bonded to each carbon atom, with a double bond between the two carbon atoms: ``` H H | | Cl -- C == C -- Cl ``` 2. In the second structure, both chlorine atoms are bonded to one carbon atom, and both hydrogen atoms are bonded to the other carbon atom, with a double bond between the two carbon atoms: ``` H Cl | | H -- C == C -- Cl ``` These two structures fulfill the requirements given in the problem.

Step by step solution

01

Understand Lewis structure

The Lewis structure is a graphical representation of the molecule where the atoms are represented by their chemical symbols, and the chemical bonds are represented by lines. The electrons that are involved in the formation of a chemical bond are called "valence electrons," and the Lewis structure helps us visualize the arrangement of these valence electrons around atoms in a molecule.
02

Identify the valence electrons

For this formula, we have two carbon atoms (C), two hydrogen atoms (H), and two chlorine atoms (Cl). Their valence electrons are as follows: - Carbon (C) has 4 valence electrons (from group 14 in the periodic table). - Hydrogen (H) has 1 valence electron (from group 1 in the periodic table). - Chlorine (Cl) has 7 valence electrons (from group 17 in the periodic table).
03

Draw the first Lewis structure

In the first structure, we will place a hydrogen atom and a chlorine atom on each carbon atom. The two carbon atoms are bonded to each other, and the bonds between them involve the sharing of two pairs of electrons. This is a double bond. Here is the Lewis structure: ``` H H | | Cl -- C == C -- Cl ```
04

Draw the second Lewis structure

In the second structure, we will place both chlorine atoms on one carbon atom and both hydrogen atoms on the other carbon atom. The two carbon atoms again form a double bond. Here is the Lewis structure: ``` H Cl | | H -- C == C -- Cl ``` These are the two possible Lewis structures for the molecule \(\mathrm{C}_{2} \mathrm{H}_{2} \mathrm{Cl}_{2}\). Keep in mind that there might be other structures as well, but the ones shown here fulfill the requirements given in the exercise.

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Most popular questions from this chapter

Predict the geometry of the following species: (a) \(\mathrm{ClF}_{2}^{-}\) (b) \(\mathrm{SeF}_{5} \mathrm{Br}\) (c) \(\mathrm{SO}_{3}^{2-}\) (d) \(\mathrm{BrO}_{2}^{-}\)

Consider the pyrosulfate ion, \(\mathrm{S}_{2} \mathrm{O}_{7}^{2-}\). It has no sulfursulfur nor oxygen-oxygen bonds. (a) Write a Lewis structure for the pyrosulfate ion using only single bonds. (b) What is the formal charge on the sulfur atoms for the Lewis structure you drew in part (a)? (c) Write another Lewis structure using six \(\mathrm{S}=\mathrm{O}\) bonds and two \(\mathrm{O}-\mathrm{S}\) bonds. (d) What is the formal charge on each atom for the structure you drew in part (c)?

There are two different molecules with the formula \(\mathrm{N}_{2} \mathrm{~F}_{2}\) Is either molecule polar? Explain.

Write the Lewis structures for the following molecules and polyatomic ions. In each case, the first atom is the central atom. (a) CCla (b) \(\mathrm{NCl}_{3}\) (c) \(\mathrm{COCl}_{2}\) (d) \(\mathrm{SO}_{3}^{2-}\)

It is possible to write a simple Lewis structure for the \(\mathrm{SO}_{4}^{2-}\) ion, involving only single bonds, which follows the octet rule. However, Linus Pauling and others have suggested an alternative structure, involving double bonds, in which the sulfur atom is surrounded by six electron pairs. (a) Draw the two Lewis structures. (b) What geometries are predicted for the two structures? (c) What is the hybridization of sulfur in each case? (d) What are the formal charges of the atoms in the two structures?

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