Chapter 4: Problem 3
Describe how you would precipitate (a) zinc carbonate from a solution of zinc nitrate. (b) copper(II) phosphate from a solution of copper(II) chloride. (c) barium sulfate from a solution of barium hydroxide.
Chapter 4: Problem 3
Describe how you would precipitate (a) zinc carbonate from a solution of zinc nitrate. (b) copper(II) phosphate from a solution of copper(II) chloride. (c) barium sulfate from a solution of barium hydroxide.
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Get started for freeTen \(\mathrm{mL}\) of concentrated \(\mathrm{H}_{3} \mathrm{PO}_{4} \quad(91.7 \%\) by mass, \(d=1.69 \mathrm{~g} / \mathrm{mL})\) was accidentally poured into a beaker containing \(20.0 \mathrm{~g}\) of \(\mathrm{NaOH} .\) Not all the \(\mathrm{NaOH}\) was consumed. How many grams of \(\mathrm{NaOH}\) were left unreacted? The equation for the reaction is $$ \mathrm{H}_{3} \mathrm{PO}_{4}(a q)+3 \mathrm{OH}^{-}(a q) \longrightarrow 3 \mathrm{H}_{2} \mathrm{O}+\mathrm{PO}_{4}^{3-}(a q) $$
A student is given \(0.930 \mathrm{~g}\) of an unknown acid, which can be either oxalic acid, \(\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4},\) or citric acid, \(\mathrm{H}_{3} \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{O}_{7}\). To determine which acid she has, she titrates the unknown acid with \(0.615 \mathrm{M} \mathrm{NaOH}\). The equivalence point is reached when \(33.6 \mathrm{~mL}\) are added. What is the unknown acid?
Consider several \(25.00-\mathrm{mL}\) solutions of perchloric acid. What is the molarity of the acid solution neutralized by (a) \(17.25 \mathrm{~mL}\) of \(0.3471 \mathrm{M}\) ethylamine \(\left(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{NH}_{2}\right)\). (b) \(14.17 \mathrm{~g}\) of strontium hydroxide. (c) \(41.73 \mathrm{~mL}\) of an \(18 \%\) (by mass) solution of ammonia \((d=0.9295 \mathrm{~g} / \mathrm{mL})\)
Write a balanced net ionic equation for each of the following reactions in water. (a) acetic acid, \(\mathrm{HC}_{2} \mathrm{H}_{3} \mathrm{O}_{2},\) with strontium hydroxide (b) diethylamine, \(\left(\mathrm{C}_{2} \mathrm{H}_{5}\right) \mathrm{NH}\) with sulfuric acid (c) aqueous hydrofluoric acid with sodium hydroxide
Consider the following generic equation: $$For which of the following pairs would this be the correct prototype equation for the acid-base reaction in solution? If it is not correct, write the proper equation for the acid-base reaction between the pair. (a) nitric acid and calcium hydroxide (b) hydrochloric acid and \(\mathrm{CH}_{3} \mathrm{NH}_{2}\) (c) hydrobromic acid and aqueous ammonia (d) perchloric acid and barium hydroxide (e) sodium hydroxide and nitrous acid\mathrm{H}^{+}(a q)+\mathrm{B}^{-}(a q) \longrightarrow \mathrm{HB}(a q)$$
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