71\. Calcium in blood or urine can be determined by precipitation as calcium
oxalate, \(\mathrm{CaC}_{2} \mathrm{O}_{4} .\) The precipitate is dissolved in
strong acid and titrated with potassium permanganate. The equation for
reaction is
$$
\begin{aligned}
2 \mathrm{MnO}_{4}^{-}(a q)+6 \mathrm{H}^{+}(a q)+& 5 \mathrm{H}_{2}
\mathrm{C}_{2} \mathrm{O}_{4}(a q) \longrightarrow \\
& 2 \mathrm{Mn}^{2+}(a q)+10 \mathrm{CO}_{2}(g)+8 \mathrm{H}_{2} \mathrm{O}
\end{aligned}
$$
A 24 -hour urine sample is collected from an adult patient, reduced to a small
volume, and titrated with \(26.2 \mathrm{~mL}\) of \(0.0946 \mathrm{M}
\mathrm{KMnO}_{4}\). How many grams of calcium oxalate are in the sample?
Normal range for \(\mathrm{Ca}^{2+}\) output for an adult is 100 to \(300
\mathrm{mg}\) per 24 hour. Is the sample within the normal range?