Chapter 21: Problem 4
Write the formula for each of the following compounds. (a) potassium bromite (b) calcium bromide (c) sodium periodate (d) magnesium hypochlorite
Chapter 21: Problem 4
Write the formula for each of the following compounds. (a) potassium bromite (b) calcium bromide (c) sodium periodate (d) magnesium hypochlorite
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Get started for freeWrite the formula of a compound of hydrogen with (a) nitrogen, which is a gas at \(25^{\circ} \mathrm{C}\) and \(1 \mathrm{~atm}\). (b) phosphorus, which is a liquid at \(25^{\circ} \mathrm{C}\) and \(1 \mathrm{~atm}\). (c) oxygen, which contains an \(\mathrm{O}-\mathrm{O}\) bond.
A \(1.500-\mathrm{g}\) sample containing sodium nitrate was heated to form \(\mathrm{NaNO}_{2}\) and \(\mathrm{O}_{2}\). The oxygen evolved was collected over water at \(23^{\circ} \mathrm{C}\) and \(752 \mathrm{~mm} \mathrm{Hg} ;\) its volume was \(125.0 \mathrm{~mL} .\) Calculate the percentage of \(\mathrm{NaNO}_{3}\) in the sample. The vapor pressure of water at \(23^{\circ} \mathrm{C}\) is \(21.07 \mathrm{~mm} \mathrm{Hg}\).
Give the Lewis structure of (a) \(\mathrm{NO}_{2}\) (b) \(\mathrm{NO}\) (c) \(\mathrm{SO}_{2}\) (d) \(\mathrm{SO}_{2}\)
The amount of sodium hypochlorite in a bleach solution can be determined by using a given volume of bleach to oxidize excess iodide ion to iodine; \(\mathrm{ClO}^{-}\) is reduced to \(\mathrm{Cl}^{-}\). The amount of iodine produced by the redox reaction is determined by titration with sodium thiosulfate, \(\mathrm{Na}_{2} \mathrm{~S}_{2} \mathrm{O}_{3} ; \mathrm{I}_{2}\) is reduced to \(1^{-}\). The sodium thiosulfate is oxidized to sodium tetrathionate, \(\mathrm{Na}_{2} \mathrm{~S}_{4} \mathrm{O}_{6} .\) In this analysis, potassium iodide was added in excess to \(5.00 \mathrm{~mL}\) of bleach \(\left(d=1.00 \mathrm{~g} / \mathrm{cm}^{3}\right)\). If \(25.00 \mathrm{~mL}\) of \(0.0700 \mathrm{M} \mathrm{Na}_{2} \mathrm{~S}_{2} \mathrm{O}_{3}\) was required to reduce all the iodine produced by the bleach back to iodide, what is the mass percent of \(\mathrm{NaClO}\) in the bleach?
Iodine can be prepared by allowing an aqueous solution of hydrogen iodide to react with manganese dioxide, \(\mathrm{MnO}_{2}\). The reaction is \(2 I^{-}(a q)+4 \mathrm{H}^{+}(a q)+\mathrm{MnO}_{2}(s) \longrightarrow \mathrm{Mn}^{2+}(a q)+2 \mathrm{H}_{2} \mathrm{O}+\mathrm{I}_{2}(s)\) If an excess of hydrogen iodide is added to \(0.200 \mathrm{~g}\) of \(\mathrm{MnO}_{2}\), how many grams of iodine are obtained, assuming \(100 \%\) yield?
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