Chapter 19: Problem 13
What is the mass percent of sulfur in the \(\left[\mathrm{Ag}(\mathrm{SCN})_{2}^{-}\right]\) complex ion?
Chapter 19: Problem 13
What is the mass percent of sulfur in the \(\left[\mathrm{Ag}(\mathrm{SCN})_{2}^{-}\right]\) complex ion?
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For complexes of \(\mathrm{V}^{3+}\), only one distribution of electrons is possible. Explain.
Platinum(II) forms many complexes, among them those with the following ligands. Give the formula and charge of each complex. (a) two ammonia molecules and one oxalate ion \(\left(\mathrm{C}_{2} \mathrm{O}_{4}^{2-}\right)\) (b) two ammonia molecules, one thiocyanate ion \(\left(\mathrm{SCN}^{-}\right),\) and one bromide ion (c) one ethylenediamine molecule and two nitrite ions
Sketch the geometry of (a) trans-[Cu(Br) \(\left._{2}\left(\mathrm{H}_{2} \mathrm{O}\right)_{4}\right]\) (b) \(\left[\mathrm{Zn}(\mathrm{OH})_{2} \mathrm{I}_{2}^{2-}\right]\) (tetrahedral) (c) \(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{4}^{2+}\right]\) (square planar) (d) \(\mathrm{cis}-\left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{2}\left(\mathrm{C}_{2} \mathrm{O}_{4}\right)_{2}{ }^{2-}\right]\) (e) \(\left[\mathrm{Au}(\mathrm{CN})\left(\mathrm{NH}_{3}\right)\right]\)
Give the number of unpaired electrons in octahedral complexes with strong- field ligands for (a) \(\mathrm{Rh}^{3+}\) (b) \(\mathrm{Mn}^{3+}\) (c) \(\mathrm{Ag}^{+}\) (d) \(\mathrm{Pt}^{4+}\) (e) \(\mathrm{Au}^{3+}\)
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