Chapter 17: Problem 45
Which of the following species will be oxidized by \(1 \mathrm{M} \mathrm{HCl} ?\) (a) \(\mathrm{Au}\) (b) \(\mathrm{Mg}\) (c) \(\mathrm{Cu}\) (d) \(\mathrm{F}^{-}\)
Chapter 17: Problem 45
Which of the following species will be oxidized by \(1 \mathrm{M} \mathrm{HCl} ?\) (a) \(\mathrm{Au}\) (b) \(\mathrm{Mg}\) (c) \(\mathrm{Cu}\) (d) \(\mathrm{F}^{-}\)
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Get started for freeWrite balanced equations for the following reactions in acid solution. (a) \(\mathrm{Ni}^{2+}(a q)+\mathrm{IO}_{4}^{-}(a q) \longrightarrow \mathrm{Ni}^{3+}(a q)+\mathrm{I}^{-}(a q)\) (b) \(\mathrm{O}_{2}(g)+\mathrm{Br}^{-}(a q) \longrightarrow \mathrm{H}_{2} \mathrm{O}+\mathrm{Br}_{2}(l)\) (c) \(\mathrm{Ca}(s)+\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}(a q) \longrightarrow \mathrm{Ca}^{2+}(a q)+\mathrm{Cr}^{3+}(a q)\) (d) \(\mathrm{IO}_{3}^{-}(a q)+\mathrm{Mn}^{2+}(a q) \longrightarrow \mathrm{I}^{-}(a q)+\mathrm{MnO}_{2}(s)\)
Consider the following reaction at \(25^{\circ} \mathrm{C}\) : $$ \mathrm{O}_{2}(g)+4 \mathrm{H}^{+}(a q)+4 \mathrm{Cl}^{-}(a q) \longrightarrow 2 \mathrm{H}_{2} \mathrm{O}+2 \mathrm{Cl}_{2}(g) $$ The \(\left[\mathrm{H}^{+}\right]\) is adjusted by adding a buffer that is \(0.125 \mathrm{M}\) in lactic acid (HLac) and \(0.125 \mathrm{M}\) in sodium lactate (NaLac). The pressure of both gases is 1.00 atm and \(\left[\mathrm{Cl}^{-}\right]\) is \(0.200 \mathrm{M}\). \(\left(K_{\mathrm{a}}\right.\) for HLac is \(\left.1.4 \times 10^{-4} .\right)\) Will the cell function as a voltaic cell?
A baby's spoon with an area of \(6.25 \mathrm{~cm}^{2}\) is plated with silver from \(\mathrm{AgNO}_{3}\) using a current of \(2.00 \mathrm{~A}\) for two hours and 25 minutes. (a) If the current efficiency is \(82.0 \%\), how many grams of silver are plated? (b) What is the thickness of the silver plate formed \(\left(d=10.5 \mathrm{~g} / \mathrm{cm}^{3}\right) ?\)
Consider the reaction $$ 2 \mathrm{Cu}^{2+}(a q)+\mathrm{Sn}^{2+}(a q) \longrightarrow \mathrm{Sn}^{4+}(a q)+2 \mathrm{Cu}^{+}(a q) $$ At what concentration of \(\mathrm{Cu}^{2+}\) is the voltage zero, if all other species are at \(0.200 \mathrm{M?}\)
Consider the reaction at \(25^{\circ} \mathrm{C}\) : \(\mathrm{S}(s)+2 \mathrm{H}^{+}(a q)+2 \mathrm{Ag}(s)+2 \mathrm{Br}^{-}(a q) \longrightarrow 2 \mathrm{AgBr}(s)+\mathrm{H}_{2} \mathrm{~S}(a q)\) At what \(\mathrm{pH}\) is the voltage zero if all the species are at standard conditions?
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