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Lead is a poisonous metal that especially affects children because they retain a larger fraction of lead than adults do. Lead levels of \(0.250 \mathrm{ppm}\) in a child cause delayed cognitive development. How many moles of lead present in \(1.00 \mathrm{~g}\) of a child's blood would \(0.250 \mathrm{ppm}\) represent?

Short Answer

Expert verified
Moles of lead = (1.00 g x (0.250/1000000))/207.2 g/mol = 1.2077 × 10^-6 mol Thus, there are 1.2077 × 10^-6 moles of lead present in 1.00 g of a child's blood with a concentration of 0.250 ppm.

Step by step solution

01

Convert ppm to mass fraction

Parts per million (ppm) is a unit of concentration that indicates 1 part in 1000000 parts. We will convert the given lead concentration (0.250 ppm) to mass fraction for further calculations. 1 ppm = 1 part in 1000000 parts = 1/1000000 So, 0.250 ppm = 0.250/1000000
02

Find the mass of lead in 1.00 g of blood

Now that we have the mass fraction of lead in the blood, we will find the mass of lead in 1.00 g of blood. Mass of lead = Mass of blood x Mass fraction of lead Mass of lead = 1.00 g x (0.250/1000000)
03

Convert mass to moles using the molar mass of lead

To find the moles of lead, we will divide the mass of lead by the molar mass of lead. The molar mass of lead (Pb) is 207.2 g/mol. Moles of lead = Mass of lead / Molar mass of lead Moles of lead = (1.00 g x (0.250/1000000))/207.2 g/mol Now, calculate the moles of lead.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Cognitive Development
Lead toxicity has a significant impact on cognitive development, especially in children. Cognitive development refers to the growth and change in a child's ability to think, learn, and assess their environment. This includes critical processes such as memorization, problem-solving, and communication skills. Young children are particularly vulnerable to lead exposure because their bodies absorb and retain lead more easily than adults. This can lead to harmful effects on their developing brain.
Research shows that even low levels of lead exposure, such as 0.250 parts per million, can cause delayed cognitive development. These delays might manifest as learning disabilities, attention deficits, and behavioral issues. Affected children might have trouble with basic developmental milestones such as language skills, comprehension, and even physical coordination.
It is vital to monitor and minimize lead exposure to protect the delicate process of cognitive development in children. By doing so, we improve their potential for future academic and life success.
Parts Per Million
Understanding parts per million (ppm) is crucial when dealing with very granular measurements. Ppm is used to express dilute concentrations and is especially relevant in environmental and health sciences. It describes one unit of substance dispersed within a million units of another substance.
Essentially, 1 ppm means that for every million parts of a mixture, there is one part of the variable of interest. In the context of the exercise, this means that 0.250 ppm indicates 0.250 parts of lead per 1 million parts of blood.
  • To convert ppm to a mass fraction, the calculation involves dividing by 1,000,000.
  • In simpler terms, 0.250 ppm is expressed as 0.250/1,000,000.
This small fractional amount illustrates how even tiny concentrations of harmful substances like lead can be detected and quantified in medical and environmental tests. Accurate understanding and manipulation of ppm values are essential in scenarios where precise dosage and exposure limits are critical.
Molar Mass
The molar mass is an essential basic concept in chemistry that connects the microscopic world of atoms to the macroscopic world of grams and moles. Molar mass represents the mass of one mole of a given substance and is expressed in grams per mole (g/mol). This value is calculated by summing the masses of all the atoms in a molecule from their atomic weights on the periodic table.
For lead (Pb), the molar mass is 207.2 g/mol. Knowing this allows you to convert between the mass of a substance and the amount in moles, which is a more practical unit for stoichiometry and chemical reactions.
  • In practice, to find the moles of lead present, you take the mass of lead and divide it by its molar mass.
  • This calculation can reveal how many lead atoms are present in a sample, which is crucial for assessing exposure levels.
The precise use of molar mass is fundamental in laboratories, ensuring safety protocols are adhered to and calculations reflect the actual amounts of substances involved.

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Most popular questions from this chapter

Twenty-five milliliters of a solution \((d=1.107 \mathrm{~g} / \mathrm{mL})\) containing \(15.25 \%\) by mass of sulfuric acid is added to \(50.0 \mathrm{~mL}\) of \(2.45 \mathrm{M}\) barium chloride. (a) What is the expected precipitate? (b) How many grams of precipitate are obtained? (c) What is the chloride concentration after precipitation is complete?

The Henry's law constant for the solubility of helium gas in water is\(3.8 \times 10^{-4} \mathrm{M} / \mathrm{atm}\) at \(25^{\circ} \mathrm{C}\). (a) Express the constant for the solubility of helium gas in \(M / \mathrm{mm} \mathrm{Hg}\). (b) If the partial pressure of \(\mathrm{He}\) at \(25^{\circ} \mathrm{C}\) is \(293 \mathrm{~mm} \mathrm{Hg}\), what is the concentration of dissolved He in \(\mathrm{mol} / \mathrm{L}\) at \(25^{\circ} \mathrm{C} ?\) (c) What volume of helium gas can be dissolved in \(10.00 \mathrm{~L}\) of water at \(293 \mathrm{~mm} \mathrm{Hg}\) and \(25^{\circ} \mathrm{C}\) ? (Ignore the partial pressure of water.)

The Henry's law constant for the solubility of oxygen in water is \(3.30 \times 10^{-4} \mathrm{M} / \mathrm{atm}\) at \(12^{\circ} \mathrm{C}\) and \(2.85 \times 10^{-4} \mathrm{M} / \mathrm{atm}\) at \(22^{\circ} \mathrm{C}\). Air is \(21 \mathrm{~mol} \%\) oxygen. (a) How many grams of axygen can be dissolved in one liter of a trout stream at \(12^{\circ} \mathrm{C}\left(54^{\circ} \mathrm{F}\right)\) at an air pressure of \(1.00 \mathrm{~atm} ?\) (b) How many grams of oxygen can be dissolved per liter in the same trout stream at \(22^{\circ} \mathrm{C}\left(72^{\circ} \mathrm{F}\right)\) at the same pressure as in (a)? (c) A nuclear power plant is responsible for the stream's increase in temperature. What percentage of dissolved oxygen is lost by this increase in the stream's temperature?

Arrange \(0.30 \mathrm{~m}\) solutions of the following solutes in order of increasing freezing point and boiling point. (a) \(\mathrm{Fe}\left(\mathrm{NO}_{3}\right)_{3}\) (b) \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}\) (c) \(\mathrm{Ba}(\mathrm{OH})_{2}\) (d) \(\mathrm{CaCr}_{2} \mathrm{O}_{7}\)

Acetone, \(\mathrm{C}_{3} \mathrm{H}_{6} \mathrm{O}\), is the main ingredient of nail polish remover. A solution is made up by adding \(35.0 \mathrm{~mL}\) of acetone \((d=0.790 \mathrm{~g} / \mathrm{mL})\) to \(50.0 \mathrm{~mL}\) of ethyl alcohol, \(\mathrm{C}_{2} \mathrm{H}_{6} \mathrm{O}(d=0.789 \mathrm{~g} / \mathrm{mL})\). Assuming volumes are additive, calculate (a) the mass percent of acetone in the solution. (b) the volume percent of ethyl alcohol in the solution. (c) the mole fraction of acetone in the solution.

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