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The temperature of the cooling water as it leaves the hot engine of an automobile is 240°F. After it passes through the radiator it has a temperature of 175°F. Calculate the amount of heat transferred from the engine to the surroundings by one gallon of water with a specific heat of 4.184 J/g°C.

Short Answer

Expert verified

The heat transferred by the engine to the surroundings is 627.5 kJ.

Step by step solution

01

Heat change

Under ideal circumstances, the net heat change is zero.

\({q_{subs\tan ceM}} + {q_{subs\tan ceN}}\) = 0

M is equal to the heat lost by the substance W.

\({q_{subs\tan ceM}} = - {q_{subs\tan ceN}}\)

The negative sign merely shows that the direction of the heat flow is opposite to each other.

02

 Step 2: Calculation of the heat energy

Given information:

The density of the water = 1g/mL

The volume of the water = 1gallon = 3785.412mL

Therefore, the mass of the water = density \( \times \) volume = 3785.412\( \times \)1 = 3785.412g

The change in temperatures is given in Fahrenheit, so we need to convert it to Celsius.

Change in temperature = \({T_{final}} - {T_{initial}} = \) 79.44 – 115.55 = -36.11\(^0C\)

\({T_{initial}} = \)\(^0C = \frac{5}{9} \times {(^0}F - 32)\)= \(^0C = \frac{5}{9} \times {(^0}F - 32) = \frac{5}{9} \times (240 - 32) = {115.55^0}C\)

\({T_{final}} = \)\(^0C = \frac{5}{9} \times {(^0}F - 32)\)= \(^0C = \frac{5}{9} \times {(^0}F - 32) = \frac{5}{9} \times (175 - 32) = {79.44^0}C\)

The specific heat of the water = 4.186\(\frac{J}{{{g^0}C}}\)

Therefore, Q = \(3785.412 \times 4.186 \times ( - 36.11) = - 627491J = - 627.5kJ\)

The negative sign implies that the heat energy is released in the process.

03

The heat transferred by the engine

We know that \({q_{subs\tan ceM}} = - {q_{subs\tan ceN}}\).

The heat transferred by the engine to the surrounding = 627.5 kJ.

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Most popular questions from this chapter

The addition of 3.15g of Ba(OH)2.8H2O to a solution of 1.52g of NH4SCN in 100g of water in a calorimeter caused the temperature to fall by 3.1˚C. Assuming the specific heat of the solution and products is 4.20J/g˚C, calculate the approximate amount of heat absorbed by the reaction, which can be represented by the following equation:
Ba(OH)2.8H2O(s) + 2NH4SCN (aq) -------> Ba(SCN)2(aq) + 2NH3(aq) + 10H2O(l)

Question: Prepare a table identifying the several energy transitions that take place during a typical operation of an automobile.

How much heat is produced by combustion of 125 g of methanol under state conditions?

Aluminum chloride can be formed from its elements:

(i)\({\bf{2Al(s) + 3C}}{{\bf{l}}_{\bf{2}}}{\bf{(g)}} \to {\bf{2AlC}}{{\bf{l}}_{\bf{3}}}{\bf{(s) \Delta H^\circ = ?}}\)

Use the reactions here to determine the ΔH° for reaction(i):

\(\begin{array}{*{20}{l}}{\left( {{\bf{ii}}} \right){\rm{ }}{\bf{HCl(g)}} \to {\bf{HCl(aq) \Delta H^\circ (ii) = - 74}}{\bf{.8 kJ}}}\\{\left( {{\bf{iii}}} \right){\rm{ }}{{\bf{H}}_{\bf{2}}}{\bf{(g) + C}}{{\bf{l}}_{\bf{2}}}{\bf{(g)}} \to {\bf{2HCl(g) \Delta H^\circ (iii) = - 185 kJ}}}\\{\left( {{\bf{iv}}} \right){\rm{ }}{\bf{AlC}}{{\bf{l}}_{\bf{3}}}{\bf{(aq)}} \to {\bf{AlC}}{{\bf{l}}_{\bf{3}}}{\bf{(s) \Delta H^\circ (iv) = + 323 kJ}}}\\{\left( {\bf{v}} \right){\rm{ }}{\bf{2Al(s) + 6HCl(aq)}} \to {\bf{2AlC}}{{\bf{l}}_{\bf{3}}}{\bf{(aq) + 3}}{{\bf{H}}_{\bf{2}}}{\bf{(g) \Delta H^\circ (v) = - 1049 kJ}}}\end{array}\)

Calculate the enthalpy of combustion of propane, C3H8(g), for the formation of H2O(g) and CO2(g). The enthalpy of formation of propane is -104 kJ/mol.

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