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Heat is released when some solutions form; heat is absorbed when other solutions form. Provide a molecular explanation for the difference between these two types of spontaneous processes.

Short Answer

Expert verified

Heat is released when the total intermolecular forces (IMFs) between the solute and solvent molecules are stronger than the total IMFs in the pure solute and the pure solvent.

Step by step solution

01

Spontaneous Process

A spontaneous process is a process that occurs without the input of matter or electrical energy into the system. A spontaneous process in a completely isolated system is characterized by an increase in entropy.

02

Heat is released when solution formed

Heat is released when the total intermolecular forces (IMFs) between the solute and solvent molecules are stronger than the total IMFs in the pure solute and the pure solvent: Breaking weaker IMFs and forming stronger IMFs releases heat.

03

Heat is absorbed when solution formed

Heat is absorbed when the total Intermolecular forces between the solute and the solvent are weaker than the total of those in the pure solute and the pure solvent: Breaking stronger IMFs and forming weaker IMFs absorbs heat.

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