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Which of the principal characteristics of solutions are evident in the solutions of \({{\bf{K}}_{\bf{2}}}{\bf{C}}{{\bf{r}}_{\bf{2}}}{{\bf{O}}_{\bf{7}}}\) shown in Figure?

Short Answer

Expert verified

The solutions are the same throughout (the colour is constant throughout), and the composition of a solution of \({{\rm{K}}_{\rm{2}}}{\rm{C}}{{\rm{r}}_{\rm{2}}}{{\rm{O}}_{\rm{7}}}\)in water can vary.

Step by step solution

01

Definition of solution

A solution is a mixture of two or more substances that have been dissolved in a liquid medium.

Example, Sugar in water

To avoid confusion with a mixture, which is heterogeneous in nature having composition different throughout.

02

Solution of Potassium dichromate

Potassium Dichromate is a hexavalent chromium compound. Its oxidizing qualities are less potent than potassium permanganate.

The potassium dichromate complex,\({\rm{K2Cr2O7}}\) is ionic compound consisting of colorless potassium ions, \({{\rm{K}}^{\rm{ + }}}\) and dichromatic ions, \({\rm{Cr2O}}{{\rm{7}}^{{\rm{2 - }}}}\) .

When potassium dichromate complex dissolves in water, it dissociates and mixture of potassium ions and dichromate ions is uniformly distributed throughout as the solution dissolves and dissociates.

03

Principal characteristics of solution shown by \({{\bf{K}}_{\bf{2}}}{\bf{C}}{{\bf{r}}_{\bf{2}}}{{\bf{O}}_{\bf{7}}}\) Solution

In solution, solute particles are uniformly distributed similarly\({{\rm{K}}_{\rm{2}}}{\rm{C}}{{\rm{r}}_{\rm{2}}}{{\rm{O}}_{\rm{7}}}\)Solution.

\({\rm{K2Cr2O7}}\)solution is homogenous in nature.

In\({\rm{K2Cr2O7}}\)solution, the particle size is at atomic level.

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Most popular questions from this chapter

Question: The vapor pressure of methanol, \({\bf{C}}{{\bf{H}}_{\bf{3}}}{\bf{OH}}\) , is 94 tor at 20 ยฐC. The vapor pressure of ethanol,\({{\bf{C}}_{\bf{2}}}{{\bf{H}}_{\bf{5}}}{\bf{OH}}\) , is 44 tor at the same temperature.

(a) Calculate the mole fraction of methanol and of ethanol in a solution of 50.0 g of methanol and 50.0 g of ethanol.

(b) Ethanol and methanol form a solution that behaves like an ideal solution. Calculate the vapor pressure of methanol and of ethanol above the solution at 20 ยฐC.

(c) Calculate the mole fraction of methanol and of ethanol in the vapor above the solution.

Calculate the mole fraction of each solute and solvent:

  1. 583 g of\({{\bf{H}}_2}{\bf{S}}{{\bf{O}}_4}\)in 1.50 kg of waterโ€”the acid solution used in an automobile battery
  2. 0.86 g of NaCl in 1.00 ร— 102 g of waterโ€”a solution of sodium chloride for intravenous injection
  3. 46.85 g of codeine, \({{\bf{C}}_{{\bf{18}}}}{{\bf{H}}_{{\bf{21}}}}{\bf{N}}{{\bf{O}}_{\bf{3}}}\), in 125.5 g of ethanol, \({{\bf{C}}_{\bf{2}}}{{\bf{H}}_{\bf{5}}}{\bf{OH}}\)
  4. 25 g of I2 in 125 g of ethanol, \({{\bf{C}}_{\bf{2}}}{{\bf{H}}_{\bf{5}}}{\bf{OH}}\).

Calculate the boiling point elevation of 0.100 kg of water containing 0.010 mol of NaCl, 0.020 mol of \({\bf{N}}{{\bf{a}}_2}{\bf{S}}{{\bf{O}}_4}\), and 0.030 mol of \({\bf{MgC}}{{\bf{l}}_2}\), assuming complete dissociation of these electrolytes.

How do solutions differ from compounds? From other mixtures?

A sample of\({\bf{HgCl}}2\)weighing 9.41 g is dissolved in 32.75 g of ethanol,\({\bf{C}}2{\bf{H}}5{\bf{OH}}\)(\({\bf{Kb}}\)= 1.20 ยฐC/m). The boiling point elevation of the solution is 1.27 ยฐC. Is\({\bf{HgC}}{{\bf{l}}_{\bf{2}}}\)an electrolyte in ethanol? Show your calculations.

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