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How do the rate of a reaction and its rate constant differ?

Short Answer

Expert verified

The rate of a reaction is proportional to its rate constant, and it typically increases with the concentration of reactants.

Step by step solution

01

Rate of reaction

A rate of reaction is a change in concentration per unit of time

\(\begin{array}{l}{\bf{Rate for A }} \to {\bf{B:}}\\{\bf{Rate = }}\,\frac{{{\bf{\Delta (B)}}}}{{{\bf{\Delta t}}}}{\bf{ = - }}\frac{{{\bf{\Delta (A)}}}}{{{\bf{\Delta t}}}}\end{array}\)

The rate of a reaction is proportional to its rate constant, and it typically increases with the concentration of reactants.

02

Rate constant

Rate = K[A]m [B]n

A rate constant (K) is a characteristic property of a reaction that indicates its intrinsic speed of reaction; the high value of the rate constant is characteristic of a rapid reaction. The rate constant for a given reaction does not change unless the temperature changes.

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Most popular questions from this chapter

Use the PhET Reactions & Rates interactive simulation (http://openstaxcollege.org/l/ 16PHETreaction) to simulate a system. On the โ€œSingle collisionโ€ tab of the simulation applet, enable the โ€œEnergy viewโ€ by clicking the โ€œ+โ€ icon. Select the first A + BCโŸถAB + C reaction (A is yellow, B is purple, and C is navy blue). Using the โ€œangled shotโ€ option, try launching the A atom with varying angles, but with more Total energy than the transition state. Whathappenswhen the A atom hitstheBC molecule from different directions? Why?

Use the provided initial rate data to derive the rate law for the reaction whose equation is: \({\bf{OC}}{{\bf{l}}^ - }\)(aq) + \({{\bf{I}}^ - }\)(aq) โŸถOIโˆ’(aq) +\({\bf{C}}{{\bf{l}}^ - }\)(aq)

Trial

(\({\bf{OC}}{{\bf{l}}^ - }\)) (mol/L)

(\({{\bf{I}}^ - }\)) (mol/L)

Initial Rate (mol/L/s)

1.

0.0040

0.0020

0.00184

2.

0.0020

0.0040

0.00092

3.

0.0020

0.0020

0.00046

Determine the rate law expression and the value of the rate constant k with appropriate units for this reaction.

For each of the following reaction diagrams, estimate the activation energy \(\left( {{E_a}} \right)\)of the reaction:

Describe how graphical methods can be used to determine the order of a reaction and its rate constant from a series of data that includes the concentration of A at varying times.

Describe the effect of each of the following on the rate of the reaction of magnesium metal with a solution of hydrochloric acid: the molarity of the hydrochloric acid, the temperature of the solution, and the size of the pieces of magnesium.

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