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Graph the following data to determine whether the reaction A⟶B + C is first order.

Trial

Time(s)

(A)

1

4.0

0.220

2

8.0

0.144

3

12.0

0.110

4

16.0

0.088

5

20.0

0.074

Short Answer

Expert verified

The graph plot of ln(A) vs. t is not a straight line.

Step by step solution

01

Rate of a Reaction

The rate of reaction may be defined as the speed of the reactant reacting to give obtain in a particular reaction at a particular time. The concentration of the reactant and product are represented into mole/L.

Rate\({\bf{ = }}\,{\bf{ k}}{\left( {\bf{A}} \right)^{\bf{m}}}{\left( {\bf{B}} \right)^{\bf{n}}}^{}\)

02

First Order Reaction

The rate equation consists of initial concentration \({\left( {\bf{A}} \right)_{\bf{0}}}\)and the concentration \({\left( {\bf{A}} \right)_{\bf{t}}}\)present after any given time t can be derived for a first-order reaction. Rearrange the integrated standard linear equation format:

\({\bf{ln}}\left( {\bf{A}} \right){\bf{ = }}\left( {{\bf{ - k}}} \right)\left( {\bf{t}} \right){\bf{ + ln}}{\left( {\bf{A}} \right)_{\bf{t}}}\)

y = mx + b

03

Graph

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Most popular questions from this chapter

The rate constant for the first-order decomposition at 45 °C of dinitrogen pentoxide, N2O5, dissolved in chloroform, \({\bf{CHC}}{{\bf{l}}_3}\), is 6.2 × 10−4 min−1.

\({\bf{2}}{{\bf{N}}_{\bf{2}}}{{\bf{O}}_{\bf{5}}} \to {\bf{4N}}{{\bf{O}}_{\bf{2}}}{\bf{ + }}{{\bf{O}}_{\bf{2}}}\)

What is the rate of the reaction when \({{\bf{N}}_{\bf{2}}}{{\bf{O}}_{\bf{5}}}{\bf{\; = 0}}{\bf{.40 M}}\)

What is the rate equation for the elementary termolecular reaction A + 2B⟶products? For 3A⟶products?

Use the PhET Reactions & Rates interactive simulation (http://openstaxcollege.org/l/ 16PHETreaction) to simulate a system. On the “Single collision” tab of the simulation applet, enable the “Energy view” by clicking the “+” icon. Select the first A + BC⟶AB + C reaction (A is yellow, B is purple, and C is navy blue). Using the “angled shot” option, try launching the A atom with varying angles, but with more Total energy than the transition state. Whathappenswhen the A atom hitstheBC molecule from different directions? Why?

For each of the following reaction diagrams, estimate the activation energy \(\left( {{E_a}} \right)\) of the reaction:

The decomposition of acetaldehyde is a second-order reaction with a rate constant of \({\bf{4}}{\bf{.71 \times 1}}{{\bf{0}}^{{\bf{ - 8 }}}}{\bf{L mo}}{{\bf{l}}^{{\bf{ - 1}}}}{\bf{ s}}{{\bf{ }}^{{\bf{ - 1}}}}\). What is the instantaneous rate of decomposition of acetaldehyde in a solution with a concentration of \({\bf{5}}{\bf{.55 \times 1}}{{\bf{0}}^{{\bf{ - 4}}}}{\bf{M}}\)?

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