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If the rate of decomposition of ammonia, \({\bf{N}}{{\bf{H}}_{\bf{3}}}\), at 1150 K is \(2.10 \times 1{0^{ - 6}}mol/L/s\), what is the rate of production of nitrogen and hydrogen?

Short Answer

Expert verified

The rate of production of nitrogen and hydrogen \(1.05 \times 1{0^{ - 6}}mol/L/s\), \({{\bf{N}}_{\bf{2}}}\) and \(3.15 \times 1{0^{ - 6}}mol/L/s\), \({{\bf{H}}_{\bf{2}}}\).

Step by step solution

01

Rate of a Reaction

The rate of the reaction is the rate of the reaction or how fast or slow reaction can happen. The reaction involves the reactant which are bound to give product at a certain period of time.

02

Explanation

One may determine after using the stoichiometry of the reaction,

\(\begin{aligned} - 1/2 \Delta \left( {N{H_3}} \right)/\Delta t = 1/3 \Delta \left( {{N_2}} \right)/\Delta t = \Delta \left( {{H_2}} \right)/\Delta t,\\\begin{aligned}{{20}{l}} {Rate of disappearance N{H_3} = - 1/2 \Delta \left( {N{H_3}} \right) / \Delta t}\\{Rate of Formation of {N_2} = 1/3 \Delta \left( {{N_2}} \right) / \Delta t}\\{Rate of formation of {H_2} = \Delta \left( {{H_2}} \right) / \Delta t}\end{aligned}\end{aligned}\)

Therefore:

Rate of Production of \({{\bf{N}}_{\bf{2}}}\)

\(\begin{aligned}1/2 \times 2.10 \times 1{0^{ - 6}}mol {\left( {Ls} \right)^{ - 1}} = \Delta ({N_2})/\Delta t\\\Delta ({N_2})/\Delta t = 1.05 \times 1{0^{ - 6}}mol {\left( {Ls} \right)^{ - 1}}\end{aligned}\)

Rate of production of \({{\bf{H}}_{\bf{2}}}\)

\(\begin{aligned}\Delta ({H_2})/\Delta t = 3 \times 2.10 \times 1{0^{ - 6}}mol {\left( {Ls} \right)^{ - 1}}/ 2\\\Delta ({H_2})/\Delta t = 3.10 1{0^{ - 6}}mol {\left( {Ls} \right)^{ - 1}}\end{aligned}\)

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Most popular questions from this chapter

What is the half-life for the first-order decay of carbon-14?

\({{\bf{\;}}_{\bf{6}}}^{{\bf{14}}}{\bf{C}}\)โŸถ\({_{\bf{7}}^{{\bf{14}}}}{\bf{N + }}{{\bf{e}}^{\bf{ - }}}\)

The rate constant for the decay is\({\bf{1}}{\bf{.21 \times 1}}{{\bf{0}}^{{\bf{ - 4}}}}{\bf{yea}}{{\bf{r}}^{{\bf{ - 1}}}}\).

How much and in what direction will each of the following effect the rate of the reaction:

CO(g) + \({\bf{NO}}{}_{\bf{2}}\) (g)โŸถ \({\bf{CO}}{}_{\bf{2}}\) (g) + NO(g) if the rate law for the reaction is rate =\({\bf{k(NO}}{}_{\bf{2}}{{\bf{)}}^{\bf{2}}}{\bf{a}}\)?

  1. Decreasing the pressure of \({\bf{NO}}{}_{\bf{2}}\) from 0.50 atm to 0.250 atm.
  2. Increasing the concentration of CO from 0.01 M to 0.03 M.

Doubling the concentration of a reactant increases the rate of a reaction four times. With this knowledge, answer the following questions:

  1. What is the order of the reaction with respect to that reactant?
  2. Tripling the concentration of a different reactant increases the rate of a reaction three times. What is the order of the reaction with respect to that reactant?

What is the difference between average rate, initial rate, and instantaneous rate?

There are two molecules with the formula\({{\bf{C}}_{\bf{3}}}{{\bf{H}}_{\bf{6}}}\). Propene,\({\bf{C}}{{\bf{H}}_{\bf{3}}}{\bf{CH = C}}{{\bf{H}}_{\bf{2}}}\), is the monomer of the polymer polypropylene, which is used for indoor-outdoor carpets. Cyclopropane is used as an anaesthetic:

When heated to 499\({\bf{^\circ C}}\), cyclopropane rearranges (isomerizes) and forms propene with a rate constant of\({\bf{5}}{\bf{.95 \times 1}}{{\bf{0}}^{{\bf{ - 4}}}}{{\bf{s}}^{{\bf{ - 1}}}}\). What is the half-life of this reaction? What fraction of the cyclopropane remains after 0.75 h at 499.5\({\bf{^\circ C}}\)?

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