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Question:Calculate the value of the equilibrium constant \({K_P}\) for the reaction \(2NO(g) + C{l_2}(g) \rightleftharpoons 2NOCl(g)\) from these equilibrium pressures: NO, \(0.050atm;C{l_2},0.30atm;NOCl,1.2atm\)

Short Answer

Expert verified

Thevalue of equilibrium constant\(K = 1920\)

Step by step solution

01

Define Equilibrium

Equilibrium is the state in which market supply and demand balance each other, and as a result prices become stable

02

Calculating the Equilibrium constant

We need to calculate equilibrium pressure constant for following reaction

\(2NO(g) + C{l_2}(g) \rightleftharpoons 2NOCl(g)\])

this is a reverse reaction so it should be written with a double arrow. Equilibrium constant is calculated like this:

\({K_p} = \frac{{p(NOCl)_{eq}^2}}{{p{{\left( {C{l_2}} \right)}_{eq}} \cdot p(NO)_{eq}^2}}\)

03

The pressure of the compound \({p_{eq}}\)

Theis pressure of the compound in the equilibrium. We are given all the data in the task:

\(\begin{array}{*{20}{c}}{p{{(NOCl)}_{eq}} = 1.2{\rm{atm}}}\\{p{{\left( {C{l_2}} \right)}_{eq}} = 0.30{\rm{atm}}}\\{p{{(NO)}_{eq}} = 0.050{\rm{atm}}}\end{array}\)

We calculate\(\begin{array}{*{20}{c}}{{K_p} = \frac{{{{1.2}^2}}}{{0.30 \cdot {{0.050}^2}}}}\\{K = 1920}\end{array}\)

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Most popular questions from this chapter

How can the pressure of water vapor are increased in the following equilibrium?

\({H_2}O(l) \rightleftharpoons {H_2}O(g)\) \(\Delta H = 41kJ\)

The initial concentrations or pressures of reactants and products are given for each of the following systems. Calculate the reaction quotient and determine the direction in which each system will proceed to reach equilibrium.

(a) \(\begin{aligned}{}2{\rm{N}}{{\rm{H}}_3}(\;{\rm{g}}) \rightleftharpoons {{\rm{N}}_2}(\;{\rm{g}}) + 3{{\rm{H}}_2}(\;{\rm{g}})\;\;\;{K_e} b= 17;\\\;\;\;\left( {{\rm{N}}{{\rm{H}}_3}} \right) = 0.50\,M,\;\left( {{{\rm{N}}_2}} \right) = 0.15\,M,\;\left( {{{\rm{H}}_2}} \right) = 0.12\,M\end{aligned}\)

(b) \(\begin{aligned}{}2{\rm{N}}{{\rm{H}}_3}(\;g) \rightleftharpoons {{\rm{N}}_2}(\;g) + 3{{\rm{H}}_2}(\;g)\;\;\;{K_P} = 6.8 \times {10^4};\\\;\;\;\;{\rm{initial}}\;{\rm{pressures:}}\,{\kern 1pt} {\rm{N}}{{\rm{H}}_3} = 2.00\;{\rm{atm}},\;{\kern 1pt} {\kern 1pt} {{\rm{N}}_2} = 10.00\,{\rm{atm}},\;{{\rm{H}}_2} = 10.00\,{\rm{atm}}\end{aligned}\)

(c) \(\begin{aligned}{}2{\rm{S}}{{\rm{O}}_3}(\;g) \rightleftharpoons 2{\rm{S}}{{\rm{O}}_2}(\;g) + {{\rm{O}}_2}(\;g)\;\;\;{K_c} = 0.230;\\\;{\kern 1pt} {\kern 1pt} {\kern 1pt} \;\left( {{\rm{S}}{{\rm{O}}_3}} \right) = 2.00\,M,\;\left( {{\rm{S}}{{\rm{O}}_2}} \right) = 2.00\,M,\;\left( {{{\rm{O}}_2}} \right) = 2.00\,M\end{aligned}\)

(d) \(\begin{aligned}{}2{\rm{S}}{{\rm{O}}_3}(\;g) \rightleftharpoons 2{\rm{S}}{{\rm{O}}_2}(\;g) + {{\rm{O}}_2}(\;g)\;\;\;{K_p} = 6.5\;{\rm{atm}};\\\;\;\;\;{\rm{initial}}\;{\rm{pressures:}}\;{\rm{S}}{{\rm{O}}_2} = 1.00\;{\rm{atm}},\;{{\rm{O}}_2} = 1.130\;{\rm{atm}},\;{\rm{S}}{{\rm{O}}_3} = 0\;{\rm{atm}}\end{aligned}\)

(e) \(\begin{aligned}{}2{\rm{NO}}(g) + {\rm{C}}{{\rm{l}}_2}(g) \rightleftharpoons 2{\rm{NOCl}}(g)\;\;\;{K_P} = 2.5 \times {10^3};\\\;\;\;\;{\rm{initial}}\;{\rm{pressures:}}\;{\rm{NO}} = 1.00\;{\rm{atm}},{\rm{C}}{{\rm{l}}_2} = 1.00\;{\rm{atm}},\;{\rm{NOCl}} = 0\;{\rm{atm}}\end{aligned}\)

(f) \(\begin{aligned}{}{{\rm{N}}_2}(\;g) + {{\rm{O}}_2}(\;g) \rightleftharpoons 2{\rm{NO}}(g)\;\;\;{K_c} = 0.050;\\\;\;\;\;\;\left( {{{\rm{N}}_2}} \right) = 0.100M,\;\left( {{{\rm{O}}_2}} \right) = 0.200M,\;({\rm{NO}}) = 1.00M\end{aligned}\)

A sample of ammonium chloride was heated in a closed container. NH4 Cl (s)⇌ NH3 (g) + HCl(g)at equilibrium, the pressure of NH3 (g)was found to be 1.75 atm. What is the value of the equilibrium constant, Kp, for the decomposition at this temperature?

What are the concentrations of \(PC{l_5}\), \(PC{l_3}\), and \(C{l_2}\) in an equilibrium mixture produced by the decomposition of a sample of pure \(PC{l_5}\) with \([PC{l_5}] = 2.00M?\) \(PC{l_5}(g) \rightleftharpoons PC{l_3}(g) + {\mathbf{C}}{{\mathbf{l}}_{\mathbf{2}}}(g)\,\,\,\,\,\,\,\;{\mathbf{Kc}} = {\mathbf{0}}.{\mathbf{0}}211\)

Question: A 1.00-L vessel at 400 °C contains the following equilibrium concentrations: N2, 1.00M; H2, 0.50M; and NH3, 0.25M. How many moles of hydrogen must be removed from the vessel to increase the concentration of nitrogen to 1.1M?

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