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Write the reaction quotient expression for the ionization of NH3 in water:

Short Answer

Expert verified

The reaction quotient expression for the ionization of NH3 in water:

\({Q_c} = \frac{{c\left( {NH_4^ + } \right) \cdot c\left( {O{H^ - }} \right)}}{{c\left( {N{H_3}} \right) \cdot 1}}\).

Step by step solution

01

The reaction regarding the ionization of NH3 in water:

The reaction of dissociation of\({\rm{N}}{{\rm{H}}_3}\)is:

\({\rm{N}}{{\rm{H}}_3}(aq) + {{\rm{H}}_2}{\rm{O}}(l) \to {\rm{NH}}_4^ + (aq) + O{{\rm{H}}^ - }(aq)\)

(Note, there needs to be double arrow, because this is a reverse reaction).

02

The reaction quotient expression for the ionization of NH3 in water:

Equation for reaction quotient is the same as for equilibrium constant, but we don't use equilibrium concentrations, but concentrations in any time before equilibrium.

\({Q_c} = \frac{{c\left( {NH_4^ + } \right) \cdot c\left( {O{H^ - }} \right)}}{{c\left( {N{H_3}} \right)}}\)

Water is not included into the equation because it is liquid and its activity is 1,

so, it would be like this:

\({Q_c} = \frac{{c\left( {NH_4^ + } \right) \cdot c\left( {O{H^ - }} \right)}}{{c\left( {N{H_3}} \right) \cdot 1}}\).

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Most popular questions from this chapter

Question: An equilibrium is established according to the following equation

\({K_c} = 4.6\)

What will happen in a solution that is 0.20 M in each \({\rm{Hg}}_2^{2 + },{\rm{NO}}_3^ - ,{{\rm{H}}^ + },{\rm{H}}{{\rm{g}}^{2 + }}\)and \({\rm{HN}}{{\rm{O}}_2}{\rm{\;?\;}}\)

a)\({\rm{H}}{{\rm{g}}_2}^{2 + }\) will be oxidized and \({\rm{N}}{{\rm{O}}_3}\)reduced,

b) \({\rm{H}}{{\rm{g}}_2}^{2 + }\)will be oxidized and \({\rm{N}}{{\rm{O}}_3}\) oxidized.

c)\({\rm{H}}{{\rm{g}}_2}^{2 + }\)will be oxidized and \({\rm{HN}}{{\rm{O}}_2}\)reduced.

d) \({\rm{H}}{{\rm{g}}_2}^{2 + }\)will be oxidized and \({\rm{HN}}{{\rm{O}}_2}\)oxidized.

(e) There will be no change because all reactants and products have an activity of 1.

Analysis of the gases in a sealed reaction vessel containing \(N{H_3}\), \({N_2}\), and \({H_2}\) at equilibrium at \(40{0^0}C\) established the concentration of \({N_2}\) to be \(1.2M\) and the concentration of \({H_2}\) to be \(0.24M\).

\({N_2}(g) + 3{H_2}(g) \rightleftharpoons 2N{H_3}(g)\)

\({K_c} = 0.50\,at\,40{0^o}C\)

Calculate the equilibrium molar concentration of \(N{H_3}\).

At a temperature of 60 ฬŠC, the vapor pressure of water is 0.196atm. What is the value of the equilibrium constant Kp for the transformation at 60 ฬŠC? H2O (l)โ‡Œ H2O(g)

A student solved the following problem and found the equilibrium concentrations to be \(\left[ {S{O_2}} \right] = 0.590M\), \(\left[ {{O_2}} \right] = 0.0450M\), and \(\left[ {S{O_3}} \right] = 0.260M\). How could this student check the work without reworking the problem? The problem was: For the following reaction at \(60{0^0}C\):

\(2S{O_2}(g) + {O_2}(g) \rightleftharpoons 2S{O_3}(g)\)

\({K_c} = 4.32\)

What are the equilibrium concentrations of all species in a mixture that was prepared with \(\left[ {S{O_3}} \right] = 0.500M\), \(\left[ {S{O_2}} \right] = 0M\)and \(\left[ {{O_2}} \right] = 0.350M\)?

Question:Calculate the value of the equilibrium constant \({K_P}\) for the reaction \(2NO(g) + C{l_2}(g) \rightleftharpoons 2NOCl(g)\) from these equilibrium pressures: NO, \(0.050atm;C{l_2},0.30atm;NOCl,1.2atm\)

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