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Write the expression of the reaction quotient for the ionization of HOCN in water.

Short Answer

Expert verified

Therefore,the reaction quotient for the ionization of HOCN in water.

\({Q_c} = \frac{{c\left( {{H_3}{O^ + }} \right) \cdot c\left( {OC{N^ - }} \right)}}{{c(HOCN)}}\).

Step by step solution

01

Reaction regarding ionization of HOCN in water:

First, we will write reaction of dissociation:

\(HOCN(aq) + {H_2}O(l) \to {H_3}{O^ + }(aq) + OC{N^ - }(aq)\)

(Note, there needs to be double arrow, because this is a reverse reaction).

Equation for reaction quotient is the same as for equilibrium constant, but we don't use equilibrium concentrations, but concentrations in any time before equilibrium.

02

The Expression for the reaction quotient for the ionization of HOCN in water:

\({Q_c} = \frac{{c\left( {{H_3}{O^ + }} \right) \cdot c\left( {OC{N^ - }} \right)}}{{c(HOCN)}}\)

Note - water is not included into the equation because it is liquid and its activity is 1 , so it would be like this:

\({Q_c} = \frac{{c\left( {{H_3}{O^ + }} \right) \cdot c\left( {OC{N^ - }} \right)}}{{c(HOCN) \cdot 1}}\).

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Most popular questions from this chapter

What are the concentrations of \(PC{l_5}\), \(PC{l_3}\), and \(C{l_2}\) in an equilibrium mixture produced by the decomposition of a sample of pure \(PC{l_5}\) with \([PC{l_5}] = 2.00M?\) \(PC{l_5}(g) \rightleftharpoons PC{l_3}(g) + {\mathbf{C}}{{\mathbf{l}}_{\mathbf{2}}}(g)\,\,\,\,\,\,\,\;{\mathbf{Kc}} = {\mathbf{0}}.{\mathbf{0}}211\)

Calculate the pressures of all species at equilibrium in a mixture of NOCl, NO, and Cl2produced when a sample of NOCl with a pressure of 10.0 atm comes to equilibrium according to this reaction:

\(2NOCl(g) \rightleftharpoons 2NO(g) + C{l_2}(g)\quad {K_P} = 4.0 \times 1{0^{ - 4}}\)

Question:Calculate the value of the equilibrium constant \({K_P}\) for the reaction \(2NO(g) + C{l_2}(g) \rightleftharpoons 2NOCl(g)\) from these equilibrium pressures: NO, \(0.050atm;C{l_2},0.30atm;NOCl,1.2atm\)

Assume that the change in pressure of \({H_2}S\) is small enough to be neglected in the following problem.(a) Calculate the equilibrium pressures of all species in an equilibrium mixture that results from the decomposition of H2S with an initial pressure of 0.824 atm.

\(2{H_2}S(g) \rightleftharpoons 2{H_2}(g) + {S_2}(g)\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{K_p} = 2.2 \times {10^{( - 6)}}\)

(b) Show that the change is small enough to be neglected.

Question : A 0.010Msolution of the weak acid HA has an osmotic pressure (see chapter on solutions and colloids) of 0.293 atm at 25 ยฐC. A 0.010Msolution of the weak acid HB has an osmotic pressure of 0.345 atm under the same conditions.

(a) Which acid has the larger equilibrium constant for ionization

HA[HA(aq) โ‡Œ Aโˆ’(aq) + H+(aq)]or HB[HB(aq) โ‡Œ H+(aq) + Bโˆ’(aq)]?

(b) What are the equilibrium constants for the ionization of these acids?

(Hint: Remember that each solution contains three dissolved species: the weak acid (HA or HB), the conjugate base (Aโˆ’ or Bโˆ’), and the hydrogen ion (H+). Remember that osmotic pressure (like all colligative properties) is related to the total number of solute particles. Specifically for osmotic pressure, those concentrations are described by molarities.)

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