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An inventor proposes using a SHE (standard hydrogen electrode) in a new battery for smartphones that also removes toxic carbon monoxide from the air:

Anode:CO(g)+H2O(l)โ†’CO2(g)+2H+(aq)+2eโˆ’Eanodeโˆ˜=โˆ’0.53V

Cathode:2H+(aq)+2eโˆ’โ†’H2(g)Ecathodeโˆ˜=0V

___________________________________________________________

Overall:CO(g)+H2O(l)โ†’CO2(g)+H2(g)Ecellโˆ˜=+0.53V

Would this make a good battery for smartphones? Why or why not?

Short Answer

Expert verified

This battery would not be ideal for smartphones.

Step by step solution

01

Step 1: Standard hydrogen electrode:

It serves as a reference electrode against which all electrode potentials are measured. When 1atm-pressure hydrogen gas is adsorbed on a platinum electrode soaked in 1M HCl at 25โˆ˜C, it is a typical hydrogen electrode with a potential of E0=0volt.

02

Find the ideal battery for the smartphone:

  • This battery would not be ideal for smartphones because the usual voltage of smartphone batteries is between 1.25V and 1.5V this battery produces a voltage of 0.53V.
  • However, given the right concentrations of reactants, a functioning battery can most probably be constructed.

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Most popular questions from this chapter

The mass of three different metal electrodes, each from a different galvanic cell, were determined before andafter the current generated by the oxidation-reduction reaction in each cell was allowed to flow for a few minutes.The first metal electrode, given the label A, was found to have increased in mass; the second metal electrode, giventhe label B, did not change in mass; and the third metal electrode, given the label C, was found to have lost mass.

Make an educated guess as to which electrodes were active and which were inert electrodes, and which wereanode(s) and which were the cathode(s)

Determine the standard cell potential and the cell potential under the stated conditions for the electrochemical reactions described here. State whether each is spontaneous or nonspontaneous under each set of conditions at 298.15K.

(a) Hg(l)+S2โˆ’(aq,0.10M)+2Ag+(aq,0.25M)โ†’2Ag(s)+HgS(s)

(b) The galvanic cell is made from a half-cell consisting of an aluminium electrode in 0.015M aluminium nitrate solution and a half-cell consisting of a nickel electrode in 0.25M nickel(II) nitrate solution.

(c) The cell is made of a half-cell in which 1.0M aqueous bromide is oxidized to 0.11M bromine ion and a half-cell in which aluminium ion at 0.023M is reduced to aluminium metal. Assume the standard reduction potential for Br2(l) is the same as that of Br2(aq).

For the standard cell potentials given here, determine the ฮ”Gโˆ˜ for the cell in kJ.

(a) 0.000V,n=2

(b) +0.434V,n=2

(c) โˆ’2.439V,n=1

Determine ฮ”G and ฮ”Gโˆ˜ for each of the reactions in the previous problem.

Determine the overall reaction and its standard cell potential at 25 ยฐC for the reaction involving the galvanic cell in which cadmium metal is oxidized to 1 M cadmium(II) ion and a half-cell consisting of an aluminum electrode

in 1 M aluminum nitrate solution. Is the reaction spontaneous at standard conditions?

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