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An active (metal) electrode was found to gain mass as the oxidation-reduction reaction was allowed to proceed. Was the electrode part of the anode or cathode? Explain.

Short Answer

Expert verified

The active electrode that gains mass is the part of cathode.

Step by step solution

01

Define oxidation and reduction

  • A voltaic or a galvanic cellis an electrochemical cell which derives the electrical energy from the spontaneous redox chemical reactions which occur inside the cell.
  • A galvanic cell usually contains two different metals which are dipped in an electrolytic solution or of an individual half-cells having different metals and their ions present in the solution, joined by a salt-bridge or divided by a porous membrane.
02

Determine balanced reaction for each pair of half reactions in an acidic solution.  

Active electrodes are those electrodes in which the mass is found to be changes as the chemical reaction proceeds in the electrolyte solution. When the electricity is pass through a solution of an electrolyte, chemical reaction occurs at the electrodes. The electrode connected to negative terminal of battery is termed as cathode whereas that connected to positive terminal of battery is termed as anode. The positively charged ions move towards to cathode, gets reduced by gaining electrons and deposit on the electrode. Thus, the active electrode that gains mass is the part of the cathode.

The active electrode that gains mass is the part of cathode.

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Most popular questions from this chapter

Write the following balanced reactions using cell notation. Use platinum as an inert electrode, if needed.

(a) \({\rm{Mg}}(s) + {\rm{N}}{{\rm{i}}^{2 + }}(aq) \to {\rm{M}}{{\rm{g}}^{2 + }}(aq) + {\rm{Ni}}(s)\)

(b) \(2{\rm{A}}{{\rm{g}}^ + }(aq) + {\rm{Cu}}(s) \to {\rm{C}}{{\rm{u}}^{2 + }}(aq) + 2{\rm{Ag}}(s)\)

(c) \({\rm{Mn}}(s) + {\rm{Sn}}{\left( {{\rm{N}}{{\rm{O}}_3}} \right)_2}(aq) \to {\rm{Mn}}{\left( {{\rm{N}}{{\rm{O}}_3}} \right)_2}(aq) + {\rm{Au}}(s)\)

(d)\(3{\rm{CuN}}{{\rm{O}}_3}(aq) + {\rm{Au}}{\left( {{\rm{N}}{{\rm{O}}_3}} \right)_3}(aq) \to 3{\rm{Cu}}{\left( {{\rm{N}}{{\rm{O}}_3}} \right)_2}(aq) + {\rm{Au}}(s)\)

Why must the charge balance in oxidation-reduction reactions?

Consider the following metals: Ag, Au, \(Mg, Ni,\)\(and\)\(Zn\). Which of these metals could be used as a sacrificial anode in the cathodic protection of an underground steel storage tank? Steel is mostly iron, so use \( - 0.447\;{\rm{V}}\) as the standard reduction potential for steel.

For each of the following balanced half-reactions, determine whether an oxidation or reduction is occurring.

(a) \({\bf{F}}{{\bf{e}}^{{\bf{3 + }}}}{\bf{ + 3}}{{\bf{e}}^{\bf{ - }}} \to {\bf{Fe}}\)

(b) \({\bf{Cr}} \to {\bf{C}}{{\bf{r}}^{{\bf{3 + }}}}{\bf{ + 3}}{{\bf{e}}^{\bf{ - }}}\)

(c) \({\bf{MnO}}_{\bf{4}}^{{\bf{2 - }}} \to {\bf{MnO}}_{\bf{4}}^{\bf{ - }}{\bf{ + }}{{\bf{e}}^{\bf{ - }}}\)

(d) \({\bf{L}}{{\bf{i}}^{\bf{ + }}}{\bf{ + }}{{\bf{e}}^{\bf{ - }}} \to {\bf{Li}}\)

What mass of zinc is required to galvanize the top of a 3.00 m ร— 5.50 m sheet of iron to a thickness of0.100 mm of zinc? If the zinc comes from a solution of \(Zn{\left( {N{O_3}} \right)_2}\) and the current is 25.5 A, how long will it take to galvanize the top of the iron? The density of zinc is 7.140 g/cm3

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