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Two arrangements of atoms are possible for a compound with a molar mass of about\({\rm{45 g/mol}}\)that contains\({\rm{52}}{\rm{.2 \% C, 13}}{\rm{.1 \% H}}\), and\({\rm{34}}{\rm{.7 \% O}}\)by mass. Write the Lewis structures for the two molecules.

Short Answer

Expert verified

The formula is:\({{\rm{C}}_{\rm{2}}}{{\rm{H}}_{\rm{6}}}{\rm{O}}\).

The Lewis structure is:

Step by step solution

01

Define Chemical Bonding

A chemical bond is a long-term attraction between atoms, ions, or molecules that allows chemical compounds to form.

02

Writing the Lewis symbol

In a \({\rm{100}}{\rm{.0 g}}\) sample, there are \({\rm{52}}{\rm{.2 g C}}\), \({\rm{34}}{\rm{.7 g O}}\) and\({\rm{13}}{\rm{.1 g H}}\).

Now we must compute the mole of\({\rm{C}}\) and\({\rm{H}}\), which we shall accomplish by dividing their mass by their molecular weight, as follows:-

The moles of carbon are:

\(\frac{{{\rm{52}}{\rm{.2 g}}}}{{{\rm{12}}{\rm{.001 g mo}}{{\rm{l}}^{{\rm{ - 1}}}}}}{\rm{ = 4}}{\rm{.346 mol C}}\)

The moles of hydrogen are:

\(\frac{{{\rm{13}}{\rm{.1 g}}}}{{{\rm{1}}{\rm{.0079 g mo}}{{\rm{l}}^{{\rm{ - 1}}}}}}{\rm{ = 12}}{\rm{.997 mol H}}\)

The moles of oxygen are:

\(\frac{{{\rm{34}}{\rm{.7 g}}}}{{{\rm{15}}{\rm{.9994 g mo}}{{\rm{l}}^{{\rm{ - 1}}}}}}{\rm{ = 2}}{\rm{.1668 mol O}}\)

To compute the formula, divide the mole by the smallest mole:-

\(\frac{{{\rm{4}}{\rm{.346 mol}}}}{{{\rm{2}}{\rm{.1688 mol}}}}{\rm{ = 2 C}}\)

\(\frac{{{\rm{12}}{\rm{.997 mol}}}}{{{\rm{2}}{\rm{.1688 mol}}}}{\rm{ = 6 H}}\)

\(\frac{{{\rm{2}}{\rm{.1688 mol}}}}{{{\rm{2}}{\rm{.1688 mol}}}}{\rm{ = 1 O}}\)

The formula is \({{\rm{C}}_{\rm{2}}}{{\rm{H}}_{\rm{6}}}{\rm{O}}\).

The Lewis structure is as follows:-

Therefore, the formula is\({{\rm{C}}_{\rm{2}}}{{\rm{H}}_{\rm{6}}}{\rm{O}}\) and the Lewis structure are:

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Most popular questions from this chapter

Predict the electron pair geometry and the molecular structure of each of the following molecules or ions:

(a)\({\rm{S}}{{\rm{F}}_{\rm{6}}}\)

(b)\({\rm{PC}}{{\rm{l}}_{\rm{5}}}\)

(c)\({\rm{Be}}{{\rm{H}}_{\rm{2}}}\)

(d) \({\rm{CH}}_{\rm{3}}^{\rm{ + }}\)

Write the electron configuration for the monatomic ions formed from the following elements (which form the greatest concentration of monatomic ions in seawater): (a) \({\rm{Cl}}\) (b) \({\rm{Na}}\) (c) \({\rm{Mg}}\)(d) \({\rm{Ca}}\) (e) \({\rm{K}}\) (f) \({\rm{Br}}\) (g) \({\rm{Sr}}\) (h) \({\rm{F}}\).

Question: Using the bond energies in Table \({\rm{7}}{\rm{.2}}\), determine the approximate enthalpy change for each of the following reactions:

(a) \({\rm{C}}{{\rm{l}}_{\rm{2}}}{\rm{(g) + 3}}{{\rm{F}}_{\rm{2}}}{\rm{(g)}} \to {\rm{2Cl}}{{\rm{F}}_{\rm{3}}}{\rm{(g)}}\)

(b) \({{\rm{H}}_{\rm{2}}}{\rm{C = C}}{{\rm{H}}_{\rm{2}}}{\rm{(g) + }}{{\rm{H}}_{\rm{2}}}{\rm{(g)}} \to {{\rm{H}}_{\rm{3}}}{\rm{CC}}{{\rm{H}}_{\rm{3}}}{\rm{(g)}}\)

(c) \({\rm{2}}{{\rm{C}}_{\rm{2}}}{{\rm{H}}_{\rm{6}}}{\rm{(g) + 7}}{{\rm{O}}_{\rm{2}}}{\rm{(g)}} \to {\rm{4C}}{{\rm{O}}_{\rm{2}}}{\rm{(g) + 6}}{{\rm{H}}_{\rm{2}}}{\rm{O(g)}}\)

Which of the following molecules and ions contain polar bonds? Which of these molecules and ions have dipole moments?

  1. \({\rm{Cl}}{{\rm{F}}_{\rm{5}}}\)
  2. \({\rm{Cl}}{{\rm{O}}_{\rm{2}}}{\rm{ - }}\)
  3. \({\rm{TeC}}{{\rm{l}}_{\rm{4}}}^{{\rm{2 - }}}\)
  4. \({\rm{PC}}{{\rm{l}}_{\rm{3}}}\)
  5. \({\rm{Se}}{{\rm{F}}_{\rm{4}}}\)
  6. \({\rm{P}}{{\rm{H}}_{\rm{2}}}^{\rm{ - }}\)
  7. \({\rm{Xe}}{{\rm{F}}_{\rm{2}}}\)

Use the Molecule Shape simulator (http://openstaxcollege.org/l/16MolecShape) to explore real molecules. On the Real Molecules tab, select H2O. Switch between the โ€œrealโ€ and โ€œmodelโ€ modes. Explain the difference observed.

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