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Methanol,\({{\text{H}}_{\text{3}}}{\text{COH}}\), is used as the fuel in some race cars. Ethanol,\({{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}{\text{OH}}\), is used extensively as motor fuel in Brazil. Both methanol and ethanol produce\({\text{C}}{{\text{O}}_{\text{2}}}\)and\({{\text{H}}_{\text{2}}}{\text{O}}\)when they burn. Write the chemical equations for these combustion reactions using Lewis structures instead of chemical formulas.

Short Answer

Expert verified

The combustion reaction using the Lewis structure for \({\text{C}}{{\text{H}}_{\text{3}}}{\text{OH }}\) is

The combustion reaction using the Lewis structure for \({{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}{\text{OH }}\) is:


Step by step solution

01

Define Chemical Bonding

A chemical bond is a long-term inducement between atoms, ions, or molecules that permits chemical compounds to develop.

02

Writing the combustion reaction

The combustion reaction for \({\text{C}}{{\text{H}}_{\text{3}}}{\text{OH }}\) is

The combustion reaction for \({{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}{\text{OH }}\)

Therefore, the reactions are

\({\text{C}}{{\text{H}}_{\text{3}}}{\text{OH }}\)-

\({{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}{\text{OH }}\)-

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Most popular questions from this chapter

Write the electron configuration for each of the following ions: (a) \({\rm{A}}{{\rm{s}}^{{\rm{3 - }}}}\) (b) \({{\rm{I}}^{\rm{ - }}}\) (c) \({\rm{B}}{{\rm{e}}^{{\rm{2 + }}}}\) (d) \({\rm{C}}{{\rm{d}}^{{\rm{2 + }}}}\)(e) \({{\rm{O}}^{{\rm{2 - }}}}\) (f) \({\rm{G}}{{\rm{a}}^{{\rm{3 + }}}}\) (g) \({\rm{L}}{{\rm{i}}^{\rm{ + }}}\) (h) \({{\rm{N}}^{{\rm{3 - }}}}\) (i) \({\rm{S}}{{\rm{n}}^{{\rm{2 + }}}}\) (j) \({\rm{C}}{{\rm{o}}^{{\rm{2 + }}}}\) (k) \({\rm{F}}{{\rm{e}}^{{\rm{2 + }}}}\) (l) \({\rm{A}}{{\rm{s}}^{{\rm{3 + }}}}\) .

Question: Use principles of atomic structure to answer each of the following:

(a) The radius of the \({\rm{Ca}}\) atom is \({\rm{197 pm}}\); the radius of the \({\rm{C}}{{\rm{a}}^{{\rm{2 + }}}}\) ion is \({\rm{99 pm}}\). Account for the difference.

(b) The lattice energy of \({\rm{CaO(s)}}\) is \({\rm{ - 3460 kJ/mol}}\); the lattice energy of \({{\rm{K}}_{\rm{2}}}{\rm{O}}\) is \({\rm{ - 2240 kJ/mol}}\). Account for the difference.

(c) Given these ionization values, explain the difference between \({\rm{Ca}}\) and \({\rm{K}}\) with regard to their first and second ionization energies.

(d) The first ionization energy of \({\rm{Mg}}\) is \({\rm{738 kJ/mol}}\) and that of \({\rm{Al}}\) is \({\rm{578 kJ/mol}}\). Account for this difference.

Identify the atoms that correspond to each of the following electron configurations. Then, write the Lewis symbol for the common ion formed from each atom: (a)\({\text{1}}{{\text{s}}^{\text{2}}}{\text{2}}{{\text{s}}^{\text{2}}}{\text{2}}{{\text{p}}^{\text{5}}}\)(b)\({\text{1}}{{\text{s}}^{\text{2}}}{\text{2}}{{\text{s}}^{\text{2}}}{\text{2}}{{\text{p}}^{\text{6}}}{\text{3}}{{\text{s}}^{\text{2}}}\)(c)\({\text{1}}{{\text{s}}^{\text{2}}}{\text{2}}{{\text{s}}^{\text{2}}}{\text{2}}{{\text{p}}^{\text{6}}}{\text{3}}{{\text{s}}^{\text{2}}}{\text{3}}{{\text{p}}^{\text{6}}}{\text{4}}{{\text{s}}^{\text{2}}}{\text{3}}{{\text{d}}^{{\text{10}}}}\)(d)\({\text{1}}{{\text{s}}^{\text{2}}}{\text{2}}{{\text{s}}^{\text{2}}}{\text{2}}{{\text{p}}^{\text{6}}}{\text{3}}{{\text{s}}^{\text{2}}}{\text{3}}{{\text{p}}^{\text{6}}}{\text{4}}{{\text{s}}^{\text{2}}}{\text{3}}{{\text{d}}^{{\text{10}}}}{\text{4}}{{\text{p}}^{\text{4}}}\)(e)\({\text{1}}{{\text{s}}^{\text{2}}}{\text{2}}{{\text{s}}^{\text{2}}}{\text{2}}{{\text{p}}^{\text{6}}}{\text{3}}{{\text{s}}^{\text{2}}}{\text{3}}{{\text{p}}^{\text{6}}}{\text{4}}{{\text{s}}^{\text{2}}}{\text{3}}{{\text{d}}^{{\text{10}}}}{\text{4}}{{\text{p}}^{\text{1}}}\).

Question: Using the bond energies in Table \({\rm{7}}{\rm{.2}}\), determine the approximate enthalpy change for each of the following reactions:

(a) \({{\rm{H}}_{\rm{2}}}{\rm{(g) + B}}{{\rm{r}}_{\rm{2}}}{\rm{(g)}} \to {\rm{2HBr(g)}}\)

(b) \({\rm{C}}{{\rm{H}}_{\rm{4}}}{\rm{(g) + }}{{\rm{I}}_{\rm{2}}}{\rm{(g)}} \to {\rm{C}}{{\rm{H}}_{\rm{3}}}{\rm{I(g) + HI(g)}}\)

(c) \({{\rm{C}}_{\rm{2}}}{{\rm{H}}_4}{\rm{(g) + 3}}{{\rm{O}}_{\rm{2}}}{\rm{(g)}} \to {\rm{2C}}{{\rm{O}}_{\rm{2}}}{\rm{(g) + 2}}{{\rm{H}}_{\rm{2}}}{\rm{O(g)}}\)

How are single, double, and triple bonds similar? How do they differ?

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