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Write Lewis structures for: (a) \({\rm{P}}{{\rm{O}}_{\rm{4}}}^{{\rm{3 - }}}\) (b) \({\rm{IC}}{{\rm{I}}_{\rm{4}}}^{\rm{ - }}\) (c) \({\rm{S}}{{\rm{O}}_{\rm{3}}}^{{\rm{2 - }}}\) (d) \({\rm{HONO}}\) .

Short Answer

Expert verified

The Lewis structure for the following are:

Step by step solution

01

Define Chemical Bonding

Lewis structure-

Lewis dot structures are also called as electron dot structures gives diagrams that depict the chemical adhesion between atoms in a molecule.

02

Concept

The following are the steps to drawing a Lewis structure:

(1) First, determine the total number of valence electrons, then deduct one electron for each positive charge if it is a cation, or add one electron for each negative charge if it is an anion.

(2) Now, arrange the atoms around the core atom to form a skeletal structure for the molecule. The least electronegative atom is typically chosen as the center atom. Connect each atom to the core atom with a single bond now.

(3) Now, on all atoms save the center atom, distribute the remaining electrons as lone pairs to complete their octet. (With the exception of hydrogen, which only takes two electrons to complete its duplet.)

(4) Now, arrange the remaining electrons around the center atom.

(5) Now, if any atom's octet is not full, draw several bonds with the centre atom correspondingly.

03

Writing the Lewis structure

(a) The Lewis structure of the value \({\rm{P}}{{\rm{O}}_{\rm{4}}}^{{\rm{3 - }}}\) is:


04

Writing the Lewis structure

(b) The Lewis structure of the value \({\rm{IC}}{{\rm{I}}_{\rm{4}}}^{\rm{ - }}\) is:


05

Writing the Lewis structure

(c) The Lewis structure of the value \({\rm{S}}{{\rm{O}}_{\rm{3}}}^{{\rm{2 - }}}\) is:


06

Writing the Lewis structure

(d) The Lewis structure of the value \({\rm{HONO}}\) is:


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Most popular questions from this chapter

Which of the following molecules and ions contain polar bonds? Which of these molecules and ions have dipole moments?

  1. \({\rm{Cl}}{{\rm{F}}_{\rm{5}}}\)
  2. \({\rm{Cl}}{{\rm{O}}_{\rm{2}}}{\rm{ - }}\)
  3. \({\rm{TeC}}{{\rm{l}}_{\rm{4}}}^{{\rm{2 - }}}\)
  4. \({\rm{PC}}{{\rm{l}}_{\rm{3}}}\)
  5. \({\rm{Se}}{{\rm{F}}_{\rm{4}}}\)
  6. \({\rm{P}}{{\rm{H}}_{\rm{2}}}^{\rm{ - }}\)
  7. \({\rm{Xe}}{{\rm{F}}_{\rm{2}}}\)

Write the Lewis structure for the diatomic molecule \({{\rm{P}}_{\rm{2}}}\), an unstable form of phosphorus found in high temperature phosphorus vapor.

Methanol,\({{\text{H}}_{\text{3}}}{\text{COH}}\), is used as the fuel in some race cars. Ethanol,\({{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}{\text{OH}}\), is used extensively as motor fuel in Brazil. Both methanol and ethanol produce\({\text{C}}{{\text{O}}_{\text{2}}}\)and\({{\text{H}}_{\text{2}}}{\text{O}}\)when they burn. Write the chemical equations for these combustion reactions using Lewis structures instead of chemical formulas.

Which of these molecules and ions contain polar bonds? Which of these molecules and ions have dipole moments?

  1. \({{\rm{H}}_{\rm{3}}}{{\rm{O}}^{\rm{ + }}}\)
  2. \({\rm{PC}}{{\rm{l}}_{\rm{4}}}^{\rm{ - }}\)
  3. \({\rm{SnCl}}_{\rm{3}}^{\rm{ - }}\)
  4. \({\rm{BrCl}}_{\rm{4}}^{\rm{ - }}\)
  5. \({\rm{IC}}{{\rm{l}}_{\rm{3}}}\)
  6. \({\rm{Xe}}{{\rm{F}}_{\rm{4}}}\)
  7. \({\rm{S}}{{\rm{F}}_{\rm{2}}}\)

Use the simulation (http://openstaxcollege.org/l/16MolecPolarity) to perform the following exercises for a real molecule. You may need to rotate the molecules in three dimensions to see certain dipoles. (a) Sketch the bond dipoles and molecular dipole (if any) for O3. Explain your observations. (b) Look at the bond dipoles for NH3. Use these dipoles to predict whether N or H is more electronegative. (c) Predict whether there should be a molecular dipole for NH3 and, if so, in which direction it will point. Check the molecular dipole box to test your hypothesis.

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