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For the molecule allene, \({{\rm{H}}_{\rm{2}}}{\rm{C = C = C}}{{\rm{H}}_{\rm{2}}}\) , give the hybridization of each carbon atom. Will the hydrogen atoms be in the same plane or perpendicular planes?

Short Answer

Expert verified

Two \({\rm{\pi }}\) bonds bind the core carbon atom. \({\rm{\pi }}\) bonding requires perpendicular \({\rm{p}}\) orbitals. As a result, the \({\rm{C}}{{\rm{H}}_{\rm{2}}}\) planes must be perpendicular to one another, and the hydrogen atoms must be in those planes.

Step by step solution

01

Define molecule

A molecule is the smallest unit of a substance that holds the compound's chemical characteristics. Molecules are made up of atoms arranged in groups.

02

Explanation

Two \({\rm{\pi }}\) bonds connect the core carbon atom. In \({\rm{\pi }}\) bonding, the \({\rm{p}}\) orbitals must be perpendicular to each other. As a result, the \({\rm{C}}{{\rm{H}}_{\rm{2}}}\) planes must be perpendicular to one another, and the hydrogen atoms will be in those planes.

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Most popular questions from this chapter

Explain why bonds occur at specific average bond distances instead of the atoms approaching each other infinitely close.

For many years after they were discovered, it was believed that the noble gases could not form compounds. Now we know that belief to be incorrect. A mixture of xenon and fluorine gases, confined in a quartz bulb and placed on a windowsill, is found to slowly produce a white solid. Analysis of the compound indicates that it contains \({\rm{77}}{\rm{.55\% }}\)Xe and \({\rm{22}}{\rm{.45\% \;F}}\)by mass.

(a) What is the formula of the compound?

(b) Write a Lewis structure for the compound.

(c) Predict the shape of the molecules of the compound.

(d) What hybridization is consistent with the shape you predicted?

Write Lewis structures for \({\rm{N}}{{\rm{F}}_{\rm{3}}}\) and \({\rm{P}}{{\rm{F}}_{\rm{5}}}\). On the basis of hybrid orbitals, explain the fact that \({\rm{N}}{{\rm{F}}_{\rm{3}}}\), \({\rm{P}}{{\rm{F}}_{\rm{3}}}\), and \({\rm{P}}{{\rm{F}}_{\rm{5}}}\) are stable molecules, but \({\rm{N}}{{\rm{F}}_{\rm{5}}}\) does not exist.

Explain how \({\rm{\sigma }}\) and \({\rm{\pi }}\) bonds are similar and how they are different.

Draw a curve that describes the energy of a system with H and CI atoms at varying distances. Then, find the minimum energy of this curve two ways.

(a) Use the bond energy found in Table 8.1 to calculate the energy for one single HCl bond (Hint: How many bonds are in a mole?)

(b) Use the enthalpy of reaction and the bond energies for \({{\rm{H}}_{\rm{2}}}\)and \({\rm{C}}{{\rm{l}}_{\rm{2}}}\)to solve for the energy of one mole of \({\rm{HCl}}\)bonds.

\({{\text{H}}_{\text{2}}}{\text{(g) + C}}{{\text{l}}_{\text{2}}}{\text{(g)}} \rightleftharpoons {\text{2HCl(g)}}\) ฮ”Hยฐrxn = โˆ’184.7 kJ/mol

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