Question

Use structural formulas to write equations for the fol- lowing reactions. a. the substitution reaction between 2 -chloropropane and water yielding 2 -propanol and hydrogen chloride b. the addition reaction between 3 -hexene and chlorine yielding \(3,4\) -dichlorohexane

Short answer

The structural formulas for the given reactions are: a. Substitution Reaction: \[CH_3 - CHCl - CH_3 + H_2O \rightarrow CH_3 - CHOH - CH_3 + HCl\] b. Addition Reaction: \[CH_3 - CH_2 - CH = CH - CH_2 - CH_3 + Cl_2 \rightarrow CH_3 - CH_2 - CHCl - CHCl - CH_2 - CH_3\]

Step-by-step solution

Identify the reactants and products in the reaction

In this substitution reaction, 2-chloropropane will react with water to give 2-propanol and hydrogen chloride as products.

Draw the structural formulas for the reactants

The structural formulas for 2-chloropropane and water are: \[CH_3 - CHCl - CH_3 \] (2-chloropropane) \[H_2O\] (water)

Draw the structural formulas for the products

The structural formulas for 2-propanol and hydrogen chloride are: \[CH_3 - CHOH - CH_3\] (2-propanol) \[HCl\] (hydrogen chloride)

Write the equation using the structural formulas

Now, we can write the substitution reaction between 2-chloropropane and water as follows: \[CH_3 - CHCl - CH_3 + H_2O \rightarrow CH_3 - CHOH - CH_3 + HCl\] Reaction (b) - Addition Reaction

Identify the reactants and products in the reaction

Here, 3-hexene will undergo an addition reaction with chlorine, leading to the formation of 3,4-dichlorohexane as the product.

Draw the structural formulas for the reactants

The structural formulas for 3-hexene and chlorine are: \[CH_3 - CH_2 - CH = CH - CH_2 - CH_3\] (3-hexene) \[Cl_2\] (chlorine)

Draw the structural formulas for the product

The structural formula for 3,4-dichlorohexane is: \[CH_3 - CH_2 - CHCl - CHCl - CH_2 - CH_3\] (3,4-dichlorohexane)

Write the equation using the structural formulas

Finally, we can write the addition reaction between 3-hexene and chlorine as follows: \[CH_3 - CH_2 - CH = CH - CH_2 - CH_3 + Cl_2 \rightarrow CH_3 - CH_2 - CHCl - CHCl - CH_2 - CH_3\]

Key concepts

Substitution Reaction

A substitution reaction is a type of chemical reaction where one atom or group of atoms in a molecule is replaced by another atom or group. This kind of reaction is quite common in organic chemistry.

Let's break down an example of a substitution reaction to help understand better. Consider the reaction between 2-chloropropane and water, resulting in 2-propanol and hydrogen chloride.

In this reaction:

• 2-chloropropane (\[ \text{CH}_3 - \text{CHCl} - \text{CH}_3 \]) acts as the substrate.
• Water (\[ \text{H}_2\text{O} \]) provides the 'OH' group that will replace the chlorine atom.
• The products formed are 2-propanol (\[ \text{CH}_3 - \text{CHOH} - \text{CH}_3 \]) and hydrogen chloride (\[ \text{HCl} \]).

The chlorine (Cl) atom is replaced by the hydroxyl group (OH), demonstrating a key feature of a substitution reaction. Understanding the molecular structure involved helps with predicting the products of such reactions.

Addition Reaction

An addition reaction involves the combination of molecules, where atoms or groups are added to a molecule without removing any part of the initial molecule. This type of reaction is especially significant in the context of unsaturated compounds, like alkenes and alkynes.

To illustrate, let's examine the reaction between 3-hexene and chlorine, forming 3,4-dichlorohexane.

Here's what happens:

• 3-hexene (\[ \text{CH}_3 - \text{CH}_2 - \text{CH} = \text{CH} - \text{CH}_2 - \text{CH}_3 \]) has a double bond that is reactive.
• Chlorine (\[ \text{Cl}_2 \]) participates by breaking the double bond to form new single bonds.
• This generates 3,4-dichlorohexane (\[ \text{CH}_3 - \text{CH}_2 - \text{CHCl} - \text{CHCl} - \text{CH}_2 - \text{CH}_3 \]).

In an addition reaction, new atoms fill the space provided by breaking double bonds, which can alter the saturation level of the molecule. This illustrates how molecules can be transformed through such interactions.

Structural Formulas

Structural formulas are diagrams used to represent the arrangement of atoms within a molecule. These help us visualize the molecule's geometry and the types of bonds between atoms, providing great insight into their interactions in chemical reactions.

In the context of substitution and addition reactions:

• Structural formulas differ from molecular formulas in that they show how the atoms are connected, not just their numbers.
• For organic molecules, they display how the carbon skeleton is assembled.
• They can also illustrate changes in the molecules, such as breaking a bond in an addition reaction or replacing a group in a substitution reaction.

By drawing structural formulas, we can easily see the transformation from reactants to products. This clarity helps in predicting reaction outcomes and understanding molecular behavior in organic chemistry.

Organic Chemistry

Organic chemistry is the branch of chemistry that studies the structure, properties, composition, reactions, and synthesis of organic compounds, which by definition contain carbon. This field is vast and includes several types of reactions including substitution and addition reactions, as discussed.

Here are a few fundamental aspects:

• Organic compounds mainly consist of carbon atoms connected by covalent bonds to hydrogen, and sometimes include other elements such as oxygen, nitrogen, and halogens.
• This field explores a wide variety of complex compounds and reactions, focusing on lifecycle processes in living organisms but also material sciences.
• Substitution and addition reactions are core processes studied in organic chemistry, as they allow for the transformation of simple molecules into more complex structures.

By understanding the foundational reactions in organic chemistry, like substitution and addition, we can comprehend how biological molecules form and interact, as well as synthetically produce useful materials.