Chapter 10: Problem 171
Artificial Sweetener Determine the percent composition of aspartame \(\left(\mathrm{C}_{14} \mathrm{H}_{18} \mathrm{N}_{2} \mathrm{O}_{5}\right),\) an artificial sweetener.
Short Answer
Expert verified
The percent composition of aspartame \(\mathrm{C}_{14} \mathrm{H}_{18} \mathrm{N}_{2} \mathrm{O}_{5}\) is approximately:
Carbon: \(57.10\%\)
Hydrogen: \(6.16\%\)
Nitrogen: \(9.52\%\)
Oxygen: \(27.22\%\)
Step by step solution
01
Find the molar mass of aspartame
First, we need to find the molar mass of the aspartame molecule. We can do this by adding up the molar masses of each element in the molecule, taking into account the number of each element.
Molar mass of aspartame = \(\mathrm{C} * \mathrm{H} * \mathrm{N} * \mathrm{O}\)
The molar masses of each element are:
Carbon (C) = 12.01 g/mol
Hydrogen (H) = 1.008 g/mol
Nitrogen (N) = 14.01 g/mol
Oxygen (O) = 16.00 g/mol
Molar mass of aspartame = (14 * 12.01 g/mol) + (18 * 1.008 g/mol) + (2 * 14.01 g/mol) + (5 * 16.00 g/mol)
02
Calculate the mass of individual elements
Next, we will find the mass of each element in aspartame.
Mass of Carbon = 14 * 12.01 g/mol = 168.14 g/mol
Mass of Hydrogen = 18 * 1.008 g/mol = 18.144 g/mol
Mass of Nitrogen = 2 * 14.01 g/mol = 28.02 g/mol
Mass of Oxygen = 5 * 16.00 g/mol = 80.00 g/mol
03
Determine the total molar mass of aspartame
Now, we will sum up the mass of each element to find the total molar mass of aspartame.
Total Molar Mass = Mass of Carbon + Mass of Hydrogen + Mass of Nitrogen + Mass of Oxygen
Total Molar Mass = 168.14 g/mol + 18.144 g/mol + 28.02 g/mol + 80.00 g/mol
Total Molar Mass = 294.304 g/mol
04
Calculate the percent composition of each element
Finally, we will determine the percent composition of each element in aspartame. To do this, we will divide the mass of each element by the total molar mass and then multiply the result by 100.
Percent composition of Carbon = \(\frac{168.14}{294.304} * 100\% = 57.10\%\)
Percent composition of Hydrogen = \(\frac{18.144}{294.304} * 100\% = 6.16\%\)
Percent composition of Nitrogen = \(\frac{28.02}{294.304} * 100\% = 9.52\%\)
Percent composition of Oxygen = \(\frac{80.00}{294.304} * 100\% = 27.22\%\)
Thus, the percent composition of aspartame is approximately:
Carbon: \(57.10\%\)
Hydrogen: \(6.16\%\)
Nitrogen: \(9.52\%\)
Oxygen: \(27.22\%\)
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Molar Mass Calculation
Calculating the molar mass of a compound is key to understanding its composition. Here, the molar mass of aspartame needs calculation by summing up the individual molar masses of each of its elements. Aspartame's formula is \(\mathrm{C}_{14} \mathrm{H}_{18} \mathrm{N}_{2} \mathrm{O}_{5}\), indicating the number of each type of atom it contains.
To find the molar mass:
This calculation lays the groundwork for deeper analysis like percent composition.
To find the molar mass:
- Multiply the number of each element by its atomic mass (found on the periodic table).
- Carbon (C) has an atomic mass of \(12.01\, \text{g/mol}\).
- Hydrogen (H) is \(1.008\, \text{g/mol}\).
- Nitrogen (N) is \(14.01\, \text{g/mol}\).
- Oxygen (O) is \(16.00\, \text{g/mol}\).
- Carbon: \(14 \times 12.01 = 168.14\, \text{g/mol}\)
- Hydrogen: \(18 \times 1.008 = 18.144\, \text{g/mol}\)
- Nitrogen: \(2 \times 14.01 = 28.02\, \text{g/mol}\)
- Oxygen: \(5 \times 16.00 = 80.00\, \text{g/mol}\)
This calculation lays the groundwork for deeper analysis like percent composition.
Chemical Formula Interpretation
Understanding a chemical formula helps decipher what a compound is composed of. The chemical formula provides a snapshot of how many atoms of each element are in a molecule.
For aspartame, the formula \(\mathrm{C}_{14} \mathrm{H}_{18} \mathrm{N}_{2} \mathrm{O}_{5}\) tells us the following:
For aspartame, the formula \(\mathrm{C}_{14} \mathrm{H}_{18} \mathrm{N}_{2} \mathrm{O}_{5}\) tells us the following:
- There are 14 carbon atoms.
- There are 18 hydrogen atoms.
- There are 2 nitrogen atoms.
- There are 5 oxygen atoms.
Elemental Analysis
Elemental analysis involves determining how much of each element is present in a compound compared to the whole. The goal is to find the percent composition, which indicates the percentage of the compound's total mass made up by each element.
To find the percent composition, you follow these steps:
To find the percent composition, you follow these steps:
- Calculate the mass contribution of each element using its molar mass from the formula \(\text{Mass of element} = \text{Number of atoms} \times \text{Atomic mass}\).
- Use the total molar mass of the compound as the denominator.
- For each element, divide its individual mass by the total molar mass.
- Multiply the result by 100 to convert it into a percentage.
- Carbon: \(\frac{168.14}{294.304} \times 100\% = 57.10\%\)
- Hydrogen: \(\frac{18.144}{294.304} \times 100\% = 6.16\%\)
- Nitrogen: \(\frac{28.02}{294.304} \times 100\% = 9.52\%\)
- Oxygen: \(\frac{80.00}{294.304} \times 100\% = 27.22\%\)