Chapter 8: Problem 31
Using Lewis symbols and Lewis structures, diagram the formation of \(\mathrm{SiCl}_{4}\) from \(\mathrm{Si}\) and \(\mathrm{Cl}\) atoms.
Chapter 8: Problem 31
Using Lewis symbols and Lewis structures, diagram the formation of \(\mathrm{SiCl}_{4}\) from \(\mathrm{Si}\) and \(\mathrm{Cl}\) atoms.
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Get started for free(a) Use bond enthalpies to estimatethe enthalpy change for the reaction of hydrogen with ethene: $$\mathrm{H}_{2}(\mathrm{~g})+\mathrm{C}_{2} \mathrm{H}_{4}(g) \longrightarrow \mathrm{C}_{2} \mathrm{H}_{6}(g)$$ (b) Calculate the standard enthalpy change for this reaction, using heats of formation. Why does this value differ from that calculated in (a)?
Based on Lewis structures, predict the ordering of \(\mathrm{N}-\mathrm{O}\) bond lengths in \(\mathrm{NO}^{+}, \mathrm{NO}_{2}^{-}\), and \(\mathrm{NO}_{3}^{-}\).
The compound chloral hydrate, known in detective stories as knockout drops, is composed of \(14.52 \% \mathrm{C}\), \(1.83 \% \mathrm{H}, 64.30 \% \mathrm{Cl}\), and \(19.35 \%\) O by mass and has a molarmass of \(165.4 \mathrm{~g} / \mathrm{mol} .\) (a) What is the empirical formula of this substance? (b) What is the molecular formula of this substance? (c) Draw the Lewis structure of the molecule, assuming that the \(\mathrm{Cl}\) atoms bond to a single \(C\) atom and that there are a \(C-C\) bond and two C \(-\) O bonds in the compound.
You and a partner are asked to complete a lab entitled "Fluorides of Group \(6 \mathrm{~B}\) Metals" that is scheduled to extend over two lab periods. The first lab, which is to be completed by your partner, is devoted to carrying out compositional analysis. In the second lab, you are to determine melting points. Upon going to lab you find two unlabeled vials, one containing a colorless liquid and the other a green powder. You also find the following notes in your partner's notebook-Compound 1: \(47.7 \% \mathrm{Cr}\) and \(52.3 \% \mathrm{~F}\) (by mass), Compound 2: \(45.7 \% \mathrm{Mo}\) and \(54.3 \% \mathrm{~F}\) (by mass). (a) What is the empirical formula for Compound \(1 ?\) (b) What is the empirical formula for Compound 2? (c) Upon determining the melting points of these two compounds you find that the colorless liquid solidifies at \(18^{\circ} \mathrm{C}\), while the green powder does not melt up to the maximum temperature of your apparatus, \(1200{ }^{\circ} \mathrm{C}\). What is the identity of the colorless liquid? What is the identity of the green powder? Be sure to use the appropriate naming convention depending upon whether the compound is better described as a molecular or ionic compound.
Using only the periodic table as your guide, select the most electronegative atom in each of the following sets: (a) Se, \(\mathrm{Rb}, \mathrm{O}, \mathrm{In} ;\) (b) \(\mathrm{Al}, \mathrm{Ca}, \mathrm{C}, \mathrm{Si} ;\) (c) Ge, As, P, Sn; (d) Li, \(\mathrm{Rb}, \mathrm{Be}, \mathrm{Sr}\)
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