Chapter 3: Problem 61
Aluminum sulfide reacts with water to form aluminum hydroxide and hydrogen sulfide. (a) Write the balanced chemical equation for this reaction. (b) How many grams of aluminum hydroxide are obtained from \(14.2 \mathrm{~g}\) of aluminum sulfide?
Short Answer
Expert verified
The balanced chemical equation is \(Al_2S_3 + 6H_2O \rightarrow 2Al(OH)_3 + 3H_2S\). From 14.2 g of aluminum sulfide, approximately 14.76 g of aluminum hydroxide are obtained.
Step by step solution
01
Write the balanced chemical equation
For this reaction, we recall the compounds involved:
- Aluminum sulfide (\(Al_2S_3\))
- Water (\(H_2O\))
- Aluminum hydroxide (\(Al(OH)_3\))
- Hydrogen sulfide (\(H_2S\))
Now, we combine them to create the chemical equation and balance it:
\(Al_2S_3 + 6H_2O \rightarrow 2Al(OH)_3 + 3H_2S\)
02
Calculate moles of aluminum sulfide
Given the mass of aluminum sulfide (14.2 g), we can calculate its moles using its molar mass:
Molar mass of \(Al_2S_3 = 2 \times 26.98 (Al) + 3 \times 32.07 (S) = 150.16 \mathrm{~g/mol}\)
Using the equation,
Moles of \(Al_2S_3 = \frac{Mass}{Molar Mass}\)
Moles of \(Al_2S_3 = \frac{14.2 \mathrm{~g}}{150.16 \mathrm{~g/mol}} \approx 0.0946 \mathrm{~mol}\)
03
Use stoichiometry to convert moles of aluminum sulfide to moles of aluminum hydroxide
Looking at the balanced chemical equation, we see that the stoichiometric ratio of aluminum sulfide to aluminum hydroxide is \(1:2\), meaning:
1 mole of aluminum sulfide produces 2 moles of aluminum hydroxide.
Using this information, we can determine the moles of aluminum hydroxide produced from the given moles of aluminum sulfide:
Moles of \(Al(OH)_3 = 2 \times 0.0946 \mathrm{~mol} = 0.1892 \mathrm{~mol}\)
04
Convert moles of aluminum hydroxide to grams
Now, we will convert the moles of aluminum hydroxide to grams using its molar mass:
Molar mass of \(Al(OH)_3 = 26.98 (Al) + 3 \times (15.999 \times 1.008 + 15.999)\mathrm{~g/mol} = 78.00 \mathrm{~g/mol}\)
To find the mass of aluminum hydroxide produced, we use the equation:
Mass of \(Al(OH)_3 = Moles \times Molar Mass\)
Mass of \(Al(OH)_3 = 0.1892 \mathrm{~mol} \times 78.00 \mathrm{~g/mol} \approx 14.76 \mathrm{~g}\)
So, approximately 14.76 grams of aluminum hydroxide are obtained from 14.2 grams of aluminum sulfide.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Stoichiometry
Stoichiometry is a fundamental concept in chemistry that involves the calculation of reactants and products in chemical reactions. It's like a recipe, ensuring you have the right amounts to create a chemical product without leftovers. To understand stoichiometry, imagine baking cookies. You need specific amounts of flour, sugar, and butter to make them; too much or too little of any ingredient will lead to results that are less than ideal.
In the context of a chemical reaction, stoichiometry is based on the balanced chemical equation. This equation provides the proportions, known as stoichiometric coefficients, of each substance involved. For example, in the reaction between aluminum sulfide and water to produce aluminum hydroxide and hydrogen sulfide, the balanced equation is:
In the context of a chemical reaction, stoichiometry is based on the balanced chemical equation. This equation provides the proportions, known as stoichiometric coefficients, of each substance involved. For example, in the reaction between aluminum sulfide and water to produce aluminum hydroxide and hydrogen sulfide, the balanced equation is:
- 1 molecule of \( Al_2S_3 \) reacts with 6 molecules of \( H_2O \).
- This produces 2 molecules of \( Al(OH)_3 \) and 3 molecules of \( H_2S \).
Molar Mass
Molar mass is the mass of one mole of a chemical substance. It's a crucial concept in chemistry as it allows us to convert between the mass of a substance and the amount in moles, which is essential for quantifying chemical reactions accurately.
To determine molar mass, you simply add up the atomic masses of each element in a compound according to its chemical formula. For example, the molar mass of aluminum sulfide \( (Al_2S_3) \) is calculated as follows:
\[\text{Moles} = \frac{\text{Mass in grams}}{\text{Molar mass in g/mol}}\]
Knowing the molar mass is key for solving problems related to the mass and quantity of substances in chemical reactions.
To determine molar mass, you simply add up the atomic masses of each element in a compound according to its chemical formula. For example, the molar mass of aluminum sulfide \( (Al_2S_3) \) is calculated as follows:
- Aluminum \( (Al) \) has an atomic mass of approximately 26.98 g/mol.
- Sulfur \( (S) \) has an atomic mass of approximately 32.07 g/mol.
- For \( Al_2S_3 \), it's \((2 \times 26.98) + (3 \times 32.07) = 150.16 \text{ g/mol}.\)
\[\text{Moles} = \frac{\text{Mass in grams}}{\text{Molar mass in g/mol}}\]
Knowing the molar mass is key for solving problems related to the mass and quantity of substances in chemical reactions.
Chemical Reactions
Chemical reactions are processes in which substances, known as reactants, transform into new substances, called products. These transformations involve the breaking and forming of chemical bonds, changing the identity and properties of the substances involved.
Take the reaction between aluminum sulfide and water, for example. Initially, you have aluminum sulfide and water as reactants. These then undergo a chemical reaction to form aluminum hydroxide and hydrogen sulfide as products.
Understanding chemical reactions is crucial, as they are fundamental to the study of chemistry and the explanation of many natural phenomena.
Take the reaction between aluminum sulfide and water, for example. Initially, you have aluminum sulfide and water as reactants. These then undergo a chemical reaction to form aluminum hydroxide and hydrogen sulfide as products.
- The process is represented by a balanced chemical equation: \( Al_2S_3 + 6H_2O \rightarrow 2Al(OH)_3 + 3H_2S \).
- This equation indicates not only the substances involved but also their stoichiometric relationships.
Understanding chemical reactions is crucial, as they are fundamental to the study of chemistry and the explanation of many natural phenomena.