Chapter 25: Problem 58
Write a chemical equation for the formation of methionyl glycine from the constituent amino acids.
Chapter 25: Problem 58
Write a chemical equation for the formation of methionyl glycine from the constituent amino acids.
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Get started for freeThe IUPAC name for a carboxylic acid is based on the name of the hydrocarbon with the same number of carbon atoms. The ending -oic is appended, as in ethanoic acid, which is the IUPAC name for acetic acid. Draw the structure of the following acids: (a) methanoic acid. (b) pentanoic acid, and (c) 2 -chloro-3-methyldecanoic acid
Imagine a single DNA strand containing a section with the following base sequence: \(5^{\prime}\) -GCATTGGC-3'. What is the base sequence of the complementary strand? (The two strands of DNA will come together in an antiparallel fashion: that is, \(5^{\prime}\) - \(\mathrm{TAG}=3^{\prime}\) will bind to \(3^{\prime}\) - \(\mathrm{ATC}-5^{\prime}\).)
Draw the condensed structure of the compounds formed by condensation reactions between (a) benzoic acid and ethanol, (b) ethanoic acid and methylamine, (c) acetic acid and phenol. Name the compound in each case.
(a) Draw the condensed structure of the tripeptide GlyGly-His. (b) How many different tripeptides can be made from the amino acids glycine and histidine? Give the abbreviations for each of these tripeptides, using the three-letter and one-letter codes for the amino acids.
One of the most important molecules in biochemical systems is adenosine triphosphate (ATP), for which the structure is ATP ATP is the principal carrier of biochemical energy. It is considered an energy-rich compound because the hydrolysis of ATP to yield adenosine diphosphate (ADP) and inorganic phosphate is spontaneous under aqueous biochemical conditions. (a) Write a balanced equation for the reaction of ATP with water to yield ADP and inorganic phosphate ion. [Hint: Hydrolysis reactions are just the reverse of condensation reactions(Section 22.8).] (b) What would you expect for the sign of the free-energy change for this reaction? (c) ADP can undergo further hydrolysis. What would you expect for the product of that reaction?
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