Chapter 25: Problem 13
Give the molecular formula of a hydrocarbon containing five carbon atoms that is (a) an alkane, (b) a cycloalkane, (c) an alkene, (d) an alkyne. Which are saturated and which are unsaturated hydrocarbons?
Chapter 25: Problem 13
Give the molecular formula of a hydrocarbon containing five carbon atoms that is (a) an alkane, (b) a cycloalkane, (c) an alkene, (d) an alkyne. Which are saturated and which are unsaturated hydrocarbons?
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Get started for free(a) Describe the primary, secondary, and tertiary structures of proteins. (b) Quaternary structures of proteins arise if two or more smaller polypeptides or proteins associate with each other to make an overall much larger protein structure The association is due to the same hydrogen bonding, electrostatic, and dispersion forces we have seen before. Hemoglobin, the protein used to transport oxygen molecules in our blood, is an example of a protein that has quaternary structure. Hemoglobin is a tetramer; it is made of four smaller polypeptides, two "alphas" and two "betas." (These names do not imply anything about the number of alpha helices or beta sheets in the individual polypeptides.) What kind of experiments would provide sound evidence that hemoglobin exists as a tetramer and not as one enormous polypeptide chain? You may need to look into the chemical.literature to discover techniques that chemists and biochemists use to make these decisions.
Which of the following peptides have a net positive charge at pH 7? (a) Gly- Ser-Lys, (b) Pro-Leu-Ile, (c) PheTyr-Asp.
Explain the chemical differences between DNA and RNA.
Dinitromethane, \(\mathrm{CH}_{2}\left(\mathrm{NO}_{2}\right)_{2}\) is a dangerously reactive substance that decomposes readily on warming. On the other hand, dichloromethane is relatively unreactive. Why is the nitro compound so reactive compared to the chloro compound? (Hint: Consider the oxidation numbers of the atoms involved and the possible products of decomposition.)
What are the approximate bond angles (a) about carbon in an alkane, (b) about a doubly bonded carbon atom in an alkene, (c) about a triply bonded carbon atom in an alkyne?
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