Chapter 23: Problem 9
Explain in your own words what is meant by the statement, "This ore consists of a small concentration of chalcopyrite, together with considerable gangue."
Chapter 23: Problem 9
Explain in your own words what is meant by the statement, "This ore consists of a small concentration of chalcopyrite, together with considerable gangue."
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Get started for freeThe thermodynamic stabilities of the three complexes \(\mathrm{Zn}\left(\mathrm{H}_{2} \mathrm{O}\right)_{4}^{2+}, \mathrm{Zn}\left(\mathrm{NH}_{3}\right)_{4}^{2+}\), and \(\mathrm{Zn}(\mathrm{CN})_{4}^{2-}\) increase from the \(\mathrm{H}_{2} \mathrm{O}\) to the \(\mathrm{NH}_{3}\) to the \(\mathrm{CN}^{-}\) complex. How do you expect the reduction potentials of these three complexes to compare?
Explain how the electron-sea model accounts for the high electrical and thermal conductivity of metals.
The two most important iron oxide minerals are magnetite, \(\mathrm{Fe}_{3} \mathrm{O}_{4}\), and hematite, \(\mathrm{Fe}_{2} \mathrm{O}_{3}\). One is a ferrimagnetic material, while the other is an antiferromagnetic material. (a) Based on the oxidation states of iron, which one is more likely to be ferrimagnetic? (b) Would it be possible to use magnetic fields to separate these minerals?
Write balanced chemical equations that correspond to the steps in the following brief account of the metallurgy of molybdenum: Molybdenum occurs primarily as the sulfide, \(\mathrm{MoS}_{2}\). On boiling with concentrated nitric acid, a white residue of \(\mathrm{MoO}_{3}\) is obtained. This is an acidic oxide; when it is dissolved in excess hot concentrated ammonia, ammonium molybdate crystallizes on cooling. On heating ammonium molybdate, white \(\mathrm{MoO}_{3}\) is obtained. On further heating to \(1200^{\circ} \mathrm{C}\) in hydrogen, a gray powder of metallic molybdenum is obtained.
Germanium has the same crystal structure as diamond (Figure 11.41). Based on this fact, do you think germanium is likely to exhibit metallic properties? Explain your answer.
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