Chapter 23: Problem 38
Which of the following species would you expect to possess metallic properties: (a) \(\mathrm{TiCl}_{4}\), (b) NiCo alloy, (c) \(W\), (d) \(\mathrm{Ge}\), (e) \(\mathrm{Hg}_{2}^{2+}\) ? Explain in each case.
Short Answer
Expert verified
NiCo alloy and tungsten (W) possess metallic properties, while germanium (Ge) partially possesses metallic properties. Titanium tetrachloride (\(\mathrm{TiCl}_{4}\)) and the mercury ion (\(\mathrm{Hg}_{2}^{2+}\)) do not possess metallic properties.
Step by step solution
01
(a) TiCl4
Titanium tetrachloride, \(\mathrm{TiCl}_{4}\), is a covalent compound in which titanium is bonded to four chlorine atoms. Covalent compounds generally do not possess metallic properties because their electrons are not shared freely or delocalized across the entire substance. Thus, TiCl4 does not possess metallic properties.
02
(b) NiCo alloy
An alloy is a mixture of two or more metallic elements, so by definition, alloys must possess metallic properties. In this case, NiCo is an alloy of nickel and cobalt, both of which are metallic elements. Therefore, NiCo alloy possesses metallic properties.
03
(c) W
W is the chemical symbol for tungsten, which is a pure metallic element located on the periodic table. As a metal, tungsten has the inherent properties of metals, such as electrical and thermal conductivity, malleability, ductility, and lustrous appearance. Therefore, tungsten (W) possesses metallic properties.
04
(d) Ge
Germanium (Ge) is a metalloid, which means it has properties that are intermediate between those of metals and nonmetals. While germanium does exhibit some metallic properties, such as limited electrical conductivity, it does not fully possess all the characteristics of metals. As such, we can say that germanium (Ge) only partially possesses metallic properties.
05
(e) Hg2^{2+}
Mercury (Hg) is a metallic element; however, \(\mathrm{Hg}_{2}^{2+}\) is a mercury ion with a charge of +2. Ions typically do not possess the same properties as their neutral parent atoms, especially when it comes to metallic properties. In this case, \(\mathrm{Hg}_{2}^{2+}\) has lost two electrons, which would affect its ability to conduct electricity and exhibit other metallic properties. Therefore, \(\mathrm{Hg}_{2}^{2+}\) does not possess metallic properties.
Overall, only NiCo alloy and tungsten (W) possess metallic properties, while germanium (Ge) partially possesses metallic properties, and the other species do not.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Covalent Compounds
A covalent compound is formed when two or more nonmetal atoms bond by sharing valence electrons. This electron sharing results in the formation of a stable balance between attractive and repulsive forces. Unlike metallic compounds, where electrons are free to move throughout the structure, the electrons in covalent compounds are localized between the atoms. This localized nature means covalent compounds do not conduct electricity when solid, are typically less malleable, and don't display the luster that is characteristic of metals. Substances like titanium tetrachloride, \( \mathrm{TiCl}_{4} \), are classic examples of covalent compounds and, as expected, do not possess metallic properties.
Alloy Composition
Alloys are homogeneous mixtures of two or more elements, where at least one is a metal. The structure of alloys allows them to exhibit the desired properties of its constituent metals, such as increased strength, corrosion resistance, or ductility. When metals are combined to form an alloy, like nickel and cobalt in a NiCo alloy, the resultant material retains the individual metallic properties such as electrical conductivity and luster, which are inherent to its parent metals. Since alloys are primarily composed of metallic elements, they naturally display metallic properties.
Chemical Symbols
Understanding chemical symbols is fundamental in chemistry as they provide a simple and universal way to represent elements and compounds. Each element is assigned a unique one or two-letter abbreviation based on its English or Latin name. For example, 'W' stands for tungsten, 'Ge' for germanium, and 'Hg' for mercury. These symbols are crucial when discussing the properties of elements, such as metallic characteristics. Tungsten, represented by 'W', is a metallic element known for its high melting point and is used in applications requiring materials with superior heat resistance.
Metalloids
Metalloids are elements that have properties intermediate between those of metals and nonmetals. Found along the 'staircase' line on the periodic table, metalloids such as germanium (Ge), silicon (Si), and arsenic (As) can exhibit both metallic and nonmetallic behavior. Germanium, for instance, has a metallic appearance and can conduct electricity, albeit to a lesser extent than a true metal, which makes it useful in semiconductor technology. While metalloids can show some metallic traits, they generally do not have the full range of properties seen in metals, such as high ductility or fusibility.
Metallic and Nonmetallic Elements
The periodic table is divided into metals, nonmetals, and metalloids, each category displaying unique properties. Metallic elements, which make up the majority of the periodic table, are known for their high electrical and thermal conductivity, reflectivity, malleability, ductility, and are typically solid at room temperature. Nonmetals, on the other hand, are usually poor conductors of heat and electricity and have more varied states at room temperature (solid, liquid, or gas). The mercury ion \( \mathrm{Hg}_{2}^{2+} \) would theoretically lose its metallic properties when charged, as the availability of free electrons for conduction is compromised, distinguishing it from its neutral, metallic state.