Chapter 23: Problem 20
(a) In the basic oxygen process for steel formation, what reactions cause the temperature in the converter to increase? (b) Write balanced chemical equations for the oxidation of carbon, sulfur, and silicon in the converter.
Chapter 23: Problem 20
(a) In the basic oxygen process for steel formation, what reactions cause the temperature in the converter to increase? (b) Write balanced chemical equations for the oxidation of carbon, sulfur, and silicon in the converter.
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Get started for freeTin exists in two allotropic forms: Gray tin has a diamond structure, and white tin has a close-packed structure. One of these allotropic forms is a semiconductor with a small band gap while the other is a metal. Which one is which? Which form would you expect to have the longer Sn -Sn bond distance?
In an electrolytic process nickel sulfide is oxidized in ? two-step reaction: $$ \begin{array}{r} \mathrm{Ni}_{3} \mathrm{~S}_{2}(s) \longrightarrow \mathrm{Ni}^{2+}(a q)+2 \mathrm{NiS}(s)+2 \mathrm{e}^{-} \\ \mathrm{NiS}(s) \longrightarrow \mathrm{Ni}^{2+}(a q)+\mathrm{S}(s)+2 \mathrm{e}^{-} \end{array} $$ What mass of \(\mathrm{Ni}^{2+}\) is produced in solution by passing a current of 67 A for a period of \(11.0 \mathrm{hr}\), assuming the cell is \(90 \%\) efficient?
Which of the following species would you expect to possess metallic properties: (a) \(\mathrm{TiCl}_{4}\), (b) NiCo alloy, (c) \(W\), (d) \(\mathrm{Ge}\), (e) \(\mathrm{Hg}_{2}^{2+}\) ? Explain in each case.
Sodium is a highly malleable substance, whereas sodium chloride is not. Explain this difference in properties.
The heats of atomization, \(\Delta H_{\text {atom }}\), in \(\mathrm{kJ} / \mathrm{mol}\), of the first transition series of elements are as follows: (a) Write an equation for the process involved in atomization, and describe the electronic and structural changes that occur. (b) \(\Delta H_{\text {atom }}\) varies irregularly in the series following \(\mathrm{V}\). How can this be accounted for, at least in part, using the electronic configurations of the gaseous atoms? (Hint: Recall the discussions of Sections \(6.8\)
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