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Write a balanced equation for each of the following reactions: (a) Hydrogen cyanide is formed commercially by passing a mixture of methane, ammonia, and air over a catalyst at \(800^{\circ} \mathrm{C}\). Water is a by-product of the reaction. (b) Baking soda reacts with acids to produce carbon dioxide gas. (c) When barium carbonate reacts in air with sulfur dioxide, barium sulfate and carbon dioxide form.

Short Answer

Expert verified
(a) 2 CH₄ + 2 NH₃ + 3 O₂ → 2 HCN + 6 H₂O (b) NaHCO₃ + HCl → NaCl + CO₂ + H₂O (c) BaCO₃ + SO₂ → BaSO₄ + CO₂

Step by step solution

01

Reaction (a) reactants and products

First, let's identify the reactants and products for the formation of hydrogen cyanide. The reactants are methane (CH₄), ammonia (NH₃), and air (we can assume that oxygen (O₂) is the relevant component of air for this reaction). The products are hydrogen cyanide (HCN) and water (H₂O).
02

Balanced equation for reaction (a)

Now we write the balanced chemical equation for the formation of hydrogen cyanide: 2 CH₄ + 2 NH₃ + 3 O₂ → 2 HCN + 6 H₂O This equation is balanced as there are an equal number of atoms for each element on both sides of the equation.
03

Reaction (b) reactants and products

For the reaction of baking soda (NaHCO₃) with an acid (HCl, for example), the products are carbon dioxide (CO₂), water (H₂O), and a salt (NaCl).
04

Balanced equation for reaction (b)

Next, we write the balanced chemical equation for the reaction of baking soda with an acid: NaHCO₃ + HCl → NaCl + CO₂ + H₂O This equation is balanced as there are an equal number of atoms for each element on both sides of the equation.
05

Reaction (c) reactants and products

In the reaction of barium carbonate (BaCO₃) with sulfur dioxide (SO₂), the products are barium sulfate (BaSO₄) and carbon dioxide (CO₂).
06

Balanced equation for reaction (c)

Finally, we write the balanced chemical equation for the reaction of barium carbonate with sulfur dioxide: BaCO₃ + SO₂ → BaSO₄ + CO₂ This equation is balanced as there are an equal number of atoms for each element on both sides of the equation.

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Most popular questions from this chapter

One method proposed for removing \(\mathrm{SO}_{2}\) from the flue gases of power plants involves reaction with aqueous \(\mathrm{H}_{2} \mathrm{~S}\). Elemental sulfur is the product. (a) Write a balanced chemical equation for the reaction. (b) What volume of \(\mathrm{H}_{2} \mathrm{~S}\) at \(27{ }^{\circ} \mathrm{C}\) and 740 torr would be required to remove the \(\mathrm{SO}_{2}\) formed by burning \(1.0\) ton of coal containing \(3.5 \%\) S by mass? (c) What mass of elemental sulfur is produced? Assume that all reactions are \(100 \%\) efficient.

Write the chemical formula for each of the following compounds, and indicate the oxidation state of the halogen or noble-gas atom in each: (a) chlorate ion, (b) hydroiodic acid, (c) iodine trichloride, (d) sodium hypochlorite, (e) perchloric acid, (f) xenon tetrafluoride.

The standard heats of formation of \(\mathrm{H}_{2} \mathrm{O}(\mathrm{g}), \mathrm{H}_{2} \mathrm{~S}(\mathrm{~g})\), \(\mathrm{H}_{2} \mathrm{Se}(\mathrm{g})\), and \(\mathrm{H}_{2} \mathrm{Te}(g)\) are \(-241.8,-20.17,+29.7\), and \(+99.6 \mathrm{~kJ} / \mathrm{mol}\), respectively. The enthalpies necessary to convert the elements in their standard states to one mole of gaseous atoms are \(248,277,227\), and \(197 \mathrm{~kJ} / \mathrm{mol}\) of atoms for \(\mathrm{O}, \mathrm{S}, \mathrm{Se}\), and Te, respectively. The enthalpy for dissociation of \(\mathrm{H}_{2}\) is \(436 \mathrm{~kJ} / \mathrm{mol}\). Calculate the average \(\mathrm{H}-\mathrm{O}, \mathrm{H}-\mathrm{S}, \mathrm{H}-\mathrm{Se}\), and \(\mathrm{H}-\mathrm{Te}\) bond enthalpies, and comment on their trend.

Write the Lewis structure for each of the following species, and describe its geometry: (a) \(\mathrm{HNO}_{2}\), (b) \(\mathrm{N}_{3}^{-}\), (c) \(\mathrm{N}_{2} \mathrm{H}_{5}{ }^{+}\), (d) \(\mathrm{NO}_{3}^{-}\).

Would hydrogen be a satisfactory basis for a fuel econo\(\mathrm{my}\) if the only available sources were cracking of natural gas and conversion of grain- based ethanol? Explain.

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