Chapter 20: Problem 78
(a) What is the difference between a battery and a fuel cell? (b) Can the "fuel" of a fuel cell be a solid? Explain.
Chapter 20: Problem 78
(a) What is the difference between a battery and a fuel cell? (b) Can the "fuel" of a fuel cell be a solid? Explain.
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Get started for freeElemental calcium is produced by the electrolysis of molten \(\mathrm{CaCl}_{2}\). (a) What mass of calcium can be produced by this process if a current of \(7.5 \times 10^{3} \mathrm{~A}\) is applied for \(48 \mathrm{~h}\) ? Assume that the electrolytic cell is \(68 \%\) efficient. (b) What is the total energy requirement for this electrolysis if the applied emf is \(+5.00 \mathrm{~V} ?\)
Two important characteristics of voltaic cells are their cell potential and the total charge that they can deliver. Which of these characteristics depends on theamount of reactants in the cell, and which one depends on their concentration?
For the generic reaction \(\mathrm{A}(a q)+\mathrm{B}(a q) \longrightarrow\) \(\mathrm{A}^{-}(a q)+\mathrm{B}^{+}(a q)\) for which \(E^{\circ}\) is a positive number, answer the following questions: (a) What is being oxidized, and what is being reduced? (b) If you made a voltaic cell out of this reaction, what half-reaction would be occurring at the cathode, and what half-reaction would be occurring at the anode? (c) Which half-reaction from (b) is higher in potential energy? (d) What is the sign of the free energy change for the reaction? [Sections \(20.4\) and \(20.5]\)
(a) The nonrechargeable lithium batteries used for photography use lithium metal as the anode. What advantages might be realized by using lithium rather than zinc, cadmium, lead, or nickel? (b) The rechargeable lithiumion battery does not use lithium metal as an electrode material. Nevertheless, it still has a substantial advantage over nickel-based batteries. Suggest an explanation.
(a) What is an electrolytic cell? (b) The negative terminal of a voltage source is connected to an electrode of an electrolytic cell. Is the electrode the anode or the cathode of the cell? Explain. (c) The electrolysis of water is often done with a small amount of sulfuric acid added to the water. What is the role of the sulfuric acid?
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