Chapter 20: Problem 12
(a) What is meant by the term reduction? (b) On which side of a reduction half-reaction do the electrons appear? (c) What is meant by the term reductant? (d) What is meant by the term reducing agent?
Chapter 20: Problem 12
(a) What is meant by the term reduction? (b) On which side of a reduction half-reaction do the electrons appear? (c) What is meant by the term reductant? (d) What is meant by the term reducing agent?
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Get started for freeGold exists in two common positive oxidation states, \(+1\) and \(+3\). The standard reduction potentials for these oxidation states are $$ \begin{aligned} \mathrm{Au}^{+}(a q)+\mathrm{e}^{-}-\longrightarrow \mathrm{Au}(s) & E_{\mathrm{red}}^{\circ}=+1.69 \mathrm{~V} \\ \mathrm{Au}^{3+}(a q)+3 \mathrm{e}^{-}-\ldots \mathrm{Au}(s) & E_{\mathrm{red}}^{\circ}=+1.50 \mathrm{~V} \end{aligned} $$ (a) Can you use these data to explain why gold does not tarnish in the air? (b) Suggest several substances that should be strong enough oxidizing agents to oxidize gold metal. (c) Miners obtain gold by soaking goldcontaining ores in an aqueous solution of sodium cyanide. A very soluble complex ion of gold forms in the aqueous solution because of the redox reaction $$ \begin{array}{r} 4 \mathrm{Au}(s)+8 \mathrm{NaCN}(a q)+2 \mathrm{H}_{2} \mathrm{O}(l)+\mathrm{O}_{2}(g)-\longrightarrow \\ 4 \mathrm{Na}\left[\mathrm{Au}(\mathrm{CN})_{2}\right](a q)+4 \mathrm{NaOH}(a q) \end{array} $$ What is being oxidized, and what is being reduced, in this reaction? (d) Gold miners then react the basic aqueous product solution from part (c) with Zn dust to get gold metal. Write a balanced redox reaction for this process. What is being oxidized, and what is being reduced?
This oxidation-reduction reaction in acidic solution is spontaneous: \(5 \mathrm{Fe}^{2+}(a q)+\mathrm{MnO}_{4}^{-}(a q)+8 \mathrm{H}^{+}(a q)-\rightarrow\) \(5 \mathrm{Fe}^{3+}(a q)+\mathrm{Mn}^{2+}(a q)+4 \mathrm{H}_{2} \mathrm{O}(l)\) A solution containing \(\mathrm{KMnO}_{4}\) and \(\mathrm{H}_{2} \mathrm{SO}_{4}\) is poured into one beaker, and a solution of \(\mathrm{FeSO}_{4}\) is poured into another. A salt bridge is used to join the beakers. A platinum foil is placed in each solution, and a wire that passes through a voltmeter connects the two solutions. (a) Sketch the cell, indicating the anode and the cathode, the direction of electron movement through the external circuit, and the direction of ion migrations through the solutions. (b) Sketch the process that occurs at the atomic level at the surface of the anode. (c) Calculate the emf of the cell under standard conditions. (d) Calculate the emf of the cell at \(298 \mathrm{~K}\) when the concentrations are the following: \(\mathrm{pH}=0.0, \quad\left[\mathrm{Fe}^{2+}\right]=0.10 \mathrm{M}, \quad\left[\mathrm{MnO}_{4}^{-}\right]=1.50 \mathrm{M}\) \(\left[\mathrm{Fe}^{3+}\right]=2.5 \times 10^{-4} \mathrm{M},\left[\mathrm{Mn}^{2+}\right]=0.001 \mathrm{M}\)
(a) What is meant by the term oxidation? (b) On which side of an oxidation half-reaction do the electrons appear? (c) What is meant by the term oxidant? (d) What is meant by the term oxidizing agent?
(a) Why is it impossible to measure the standard reduction potential of a single half-reaction? (b) Describe how the standard reduction potential of a half-reaction can be determined.
A voltaic cell is constructed with two silver-silver chloride electrodes, each of which is based on the following half-reaction: $$ \mathrm{AgCl}(s)+\mathrm{e}^{-}--\rightarrow \mathrm{Ag}(s)+\mathrm{Cl}^{-}(a q) $$ The two cell compartments have \(\left[\mathrm{Cl}^{-} \mathrm{J}=0.0150 \mathrm{M}\right.\) and \(\left[\mathrm{Cl}^{-}\right]=2.55 M\), respectively. (a) Which electrode is the cathode of the cell? (b) What is the standard emf of the cell? (c) What is the cell emf for the concentrations given? (d) For each electrode, predict whether [Cl \(^{-}\) ] will increase, decrease, or stay the same as the cell operates.
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