Chapter 18: Problem 7
Describe the basic goals of green chemistry. [Section 18.7]
Chapter 18: Problem 7
Describe the basic goals of green chemistry. [Section 18.7]
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Get started for free(a) What is the primary basis for the division of the atmosphere into different regions? (b) Name the regions of the atmosphere, indicating the altitude interval for each one.
The degradation of \(\mathrm{CF}_{3} \mathrm{CH}_{2} \mathrm{~F}\) (an HFC) by OH radicals in the troposphere is first order in each reactant and has a rate constant of \(k=1.6 \times 10^{8} \mathrm{M}^{-1} \mathrm{~s}^{-1}\) at \(4^{\circ} \mathrm{C}\). If the tropospheric concentrations of \(\mathrm{OH}\) and \(\mathrm{CF}_{3} \mathrm{CH}_{2} \mathrm{~F}\) are \(8.1 \times 10^{5}\) and \(63 \times 10^{8}\) molecules \(\mathrm{cm}^{-3}\), respectively, what is the rate of reaction at this temperature in \(M / \mathrm{s} ?\)
An important reaction in the formation of photochemical smog is the photodissociation of \(\mathrm{NO}_{2}\) : $$ \mathrm{NO}_{2}+h \nu \longrightarrow \mathrm{NO}(g)+\mathrm{O}(g) $$ The maximum wavelength of light that can cause this reaction is \(420 \mathrm{~nm} .\) (a) In what part of the electromagnetic spectrum is light with this wavelength found? (b) What is the maximum strength of a bond, in \(\mathrm{kJ} / \mathrm{mol}\), that can be broken by absorption of a photon of \(420-\mathrm{nm}\) light? (c) Write out the photodissociation reaction showing Lewis-dot structures.
(a) Write a chemical equation that describes the attack of acid rain on limestone, \(\mathrm{CaCO}_{3}\). (b) If a limestone sculpture were treated to form a surface layer of calcium sulfate, would this help to slow down the effects of acid rain? Explain.
The rate of solar energy striking Earth averages 169 watts per square meter. The rate of energy radiated from Earth's surface averages 390 watts per square meter. Comparing these numbers, one might expect that the planet would cool quickly, yet it does not. Why not?
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