Nitrogen dioxide \(\left(\mathrm{NO}_{2}\right)\) is the only important gaseous
species in the lower atmosphere that absorbs visible light. (a) Write the
Lewis structure(s) for \(\mathrm{NO}_{2}\). (b) How does this structure account
for the fact that \(\mathrm{NO}_{2}\) dimerizes to form \(\mathrm{N}_{2}
\mathrm{O}_{4}\) ? Based on what you can find about this dimerization reaction
in the text, would you expect to find the \(\mathrm{NO}_{2}\) that forms in an
urban environment to be in the form of dimer? Explain. (c) What would you
expect as products, if any, for the reaction of \(\mathrm{NO}_{2}\) with CO? (d)
Would you expect \(\mathrm{NO}_{2}\) generated in an urban environment to
migrate to the stratosphere? Explain.