Chapter 16: Problem 71
What is the essential structural feature of all Brensted- Lowry bases?
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chapter 16: Problem 71
What is the essential structural feature of all Brensted- Lowry bases?
These are the key concepts you need to understand to accurately answer the question.
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Get started for freeWhat are two kinds of molecules or ions that commonly function as weak bases?
Explain the following observations: (a) \(\mathrm{HNO}_{3}\) is a stronger acid than \(\mathrm{HNO}_{2} ;\) (b) \(\mathrm{H}_{2} \mathrm{~S}\) is a stronger acid than \(\mathrm{H}_{2} \mathrm{O} ;\) (c) \(\mathrm{H}_{2} \mathrm{SO}_{4}\) is a stronger acid than \(\mathrm{HSO}_{4}^{-} ;\) (d) \(\mathrm{H}_{2} \mathrm{SO}_{4}\) is a stronger acid than \(\mathrm{H}_{2} \mathrm{SeO}_{4} ;\) (e) \(\mathrm{CCl}_{3} \mathrm{COOH}\) is a stronger acid than \(\mathrm{CH}_{3} \mathrm{COOH}\)
Identify the Lewis acid and Lewis base among the reactants in each of the following reactions: (a) \(\mathrm{Fe}\left(\mathrm{ClO}_{4}\right)_{3}(s)+6 \mathrm{H}_{2} \mathrm{O}(I) \rightleftharpoons\) \(\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}^{3+}(a q)+3 \mathrm{ClO}_{4}^{-}(a q)\) (b) \(\mathrm{CN}^{-}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftharpoons \mathrm{HCN}(a q)+\mathrm{OH}^{-}(a q)\) (c) \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N}(\mathrm{~g})+\mathrm{BF}_{3}(g) \rightleftharpoons\left(\mathrm{CH}_{3}\right)_{3} \mathrm{NBF}_{3}(\mathrm{~s})\) (d) \(\mathrm{HIO}(\mathrm{lq})+\mathrm{NH}_{2}^{-(l q)} \rightleftharpoons \mathrm{NH}_{3}(l q)+\mathrm{IO}^{-}(l q)\) (Iq denotes liquid ammonia as solvent)
Designate the Brønsted-Lowry acid and the BronstedLowry base on the left side of each of the following equations, and also designate the conjugate acid and conjugate base on the right side: (a) \(\mathrm{NH}_{4}{ }^{+}(a q)+\mathrm{CN}^{-}(a q) \rightleftharpoons \mathrm{HCN}(a q)+\mathrm{NH}_{3}(a q)\) (b) \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N}(a q)+\mathrm{H}_{2} \mathrm{O}(I) \rightleftharpoons\) (c) \(\mathrm{HCHO}_{2}(a q)+\mathrm{PO}_{4}{ }^{3-}(a q) \stackrel{\left(\mathrm{CH}_{3}\right)_{3} \mathrm{NH}^{+}(a q)+\mathrm{OH}^{-}(a q)}{\mathrm{CHO}_{2}^{-}(a q)+\mathrm{HPO}_{4}{ }^{2-}(a q)}\)
The active ingredient in aspirin is acetylsalicylic acid \(\left(\mathrm{HC}_{9} \mathrm{H}, \mathrm{O}_{4}\right)\), a monoprotic acid with \(K_{a}=3.3 \times 10^{-4}\) at \(25^{\circ} \mathrm{C}\). What is the \(\mathrm{pH}\) of a solution obtained by dissolving two extra-strength aspirin tablets, containing \(500 \mathrm{mg}\) of acetylsalicylic acid each, in \(250 \mathrm{~mL}\) of water?
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