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What is the essential structural feature of all Brensted- Lowry bases?

Short Answer

Expert verified
The essential structural feature of all Brønsted-Lowry bases is the presence of a lone pair of electrons that can be used to form a bond with a hydrogen ion (H+). This allows the base to accept a proton, which is the defining characteristic of a Brønsted-Lowry base.

Step by step solution

01

Define Brønsted-Lowry Base

A Brønsted-Lowry base is a substance that accepts a hydrogen ion, also known as a proton (H+), from another substance. They are also called proton acceptors.
02

Identify the Essential Structural Feature

The essential structural feature of all Brønsted-Lowry bases is the presence of a lone pair of electrons that can be used to form a bond with a hydrogen ion (H+). This lone pair allows the base to accept a proton, which is the defining characteristic of a Brønsted-Lowry base.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Proton Acceptors
In the realm of chemistry, the term proton acceptors is intricately linked with understanding Brønsted-Lowry bases. To visualize this, imagine a dance where protons (H+) are looking for a partner to dance with. Brønsted-Lowry bases are essentially willing partners, having the capability to accept protons and form a bond.

When a Brønsted-Lowry base encounters an acid, which is a donor of protons, a chemical reaction ensues where the base accepts a proton from the acid. This transaction fundamentally changes the base into its conjugate acid and the acid into its conjugate base. It's a transformative exchange that's central to numerous reactions in chemistry, especially in aqueous solutions. For instance, when ammonia (NH3) acts as a Brønsted-Lowry base, it accepts a proton to become ammonium (NH4+).

  • A Brønsted-Lowry base must have the capacity to accept a proton.
  • This acceptance induces a significant alteration in the identity of the substances involved.
  • The process forms the core of acid-base reactions in Brønsted-Lowry theory.
Lone Pair of Electrons
Every Brønsted-Lowry base is characterized by the possession of a lone pair of electrons. This is a pair of valence electrons not shared with any other atom and is available for bonding. Imagine these electrons as an open invitation to a hydrogen ion – they are ready and waiting to pair up and create a chemical bond.

These lone electrons are pivotal because they provide a site at which the base can bond with a proton. It's akin to having an extra seat at a table, enabling you to accommodate another guest — in this case, the proton. For example, in water (H2O), the oxygen atom has two lone pairs, each of which can potentially bond with a hydrogen ion to form a hydronium ion (H3O+).

  • Lone pairs are crucial for the function of a Brønsted-Lowry base.
  • They are electrically available for initiating a bond with a proton.
  • The presence of lone pairs increases a molecule's ability to act as a base.
Hydrogen Ion (H+)
The hydrogen ion, or proton, denoted by (H+), is more than just a hydrogen atom missing its electron — it's an incredibly influential player in the field of acid-base chemistry. Its significance lies in its positive charge and small size, which make it highly reactive and a key participant in the transfer process of acid-base reactions according to Brønsted-Lowry theory.

The drama of an acid-base reaction revolves around the journey of the hydrogen ion as it seeks to bond with a base, with the base's lone electron pair acting as the landing spot for this journey. Upon bonding, the properties of the hydrogen ion are transferred to the base, thereby transforming the base into a conjugate acid. This interaction is fundamental in fields ranging from biochemistry to environmental science, influencing the pH balance within natural and artificial systems.

  • The hydrogen ion is a central figure in Brønsted-Lowry acid-base reactions.
  • Its positive charge and eagerness to form bonds make it reactive and influential.
  • The interactions involving hydrogen ions help determine the acidity or basicity of a substance.

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Most popular questions from this chapter

What are two kinds of molecules or ions that commonly function as weak bases?

Explain the following observations: (a) \(\mathrm{HNO}_{3}\) is a stronger acid than \(\mathrm{HNO}_{2} ;\) (b) \(\mathrm{H}_{2} \mathrm{~S}\) is a stronger acid than \(\mathrm{H}_{2} \mathrm{O} ;\) (c) \(\mathrm{H}_{2} \mathrm{SO}_{4}\) is a stronger acid than \(\mathrm{HSO}_{4}^{-} ;\) (d) \(\mathrm{H}_{2} \mathrm{SO}_{4}\) is a stronger acid than \(\mathrm{H}_{2} \mathrm{SeO}_{4} ;\) (e) \(\mathrm{CCl}_{3} \mathrm{COOH}\) is a stronger acid than \(\mathrm{CH}_{3} \mathrm{COOH}\)

Identify the Lewis acid and Lewis base among the reactants in each of the following reactions: (a) \(\mathrm{Fe}\left(\mathrm{ClO}_{4}\right)_{3}(s)+6 \mathrm{H}_{2} \mathrm{O}(I) \rightleftharpoons\) \(\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}^{3+}(a q)+3 \mathrm{ClO}_{4}^{-}(a q)\) (b) \(\mathrm{CN}^{-}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftharpoons \mathrm{HCN}(a q)+\mathrm{OH}^{-}(a q)\) (c) \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N}(\mathrm{~g})+\mathrm{BF}_{3}(g) \rightleftharpoons\left(\mathrm{CH}_{3}\right)_{3} \mathrm{NBF}_{3}(\mathrm{~s})\) (d) \(\mathrm{HIO}(\mathrm{lq})+\mathrm{NH}_{2}^{-(l q)} \rightleftharpoons \mathrm{NH}_{3}(l q)+\mathrm{IO}^{-}(l q)\) (Iq denotes liquid ammonia as solvent)

Designate the Brønsted-Lowry acid and the BronstedLowry base on the left side of each of the following equations, and also designate the conjugate acid and conjugate base on the right side: (a) \(\mathrm{NH}_{4}{ }^{+}(a q)+\mathrm{CN}^{-}(a q) \rightleftharpoons \mathrm{HCN}(a q)+\mathrm{NH}_{3}(a q)\) (b) \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N}(a q)+\mathrm{H}_{2} \mathrm{O}(I) \rightleftharpoons\) (c) \(\mathrm{HCHO}_{2}(a q)+\mathrm{PO}_{4}{ }^{3-}(a q) \stackrel{\left(\mathrm{CH}_{3}\right)_{3} \mathrm{NH}^{+}(a q)+\mathrm{OH}^{-}(a q)}{\mathrm{CHO}_{2}^{-}(a q)+\mathrm{HPO}_{4}{ }^{2-}(a q)}\)

The active ingredient in aspirin is acetylsalicylic acid \(\left(\mathrm{HC}_{9} \mathrm{H}, \mathrm{O}_{4}\right)\), a monoprotic acid with \(K_{a}=3.3 \times 10^{-4}\) at \(25^{\circ} \mathrm{C}\). What is the \(\mathrm{pH}\) of a solution obtained by dissolving two extra-strength aspirin tablets, containing \(500 \mathrm{mg}\) of acetylsalicylic acid each, in \(250 \mathrm{~mL}\) of water?

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