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Explain the following observations: (a) Water evaporates more quickly on a hot, dry day than on a hot, humid day. (b) It takes longer to boil water for tea at high altitudes than at lower altitudes.

Short Answer

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(a) On hot, dry days, the air has lower humidity, allowing it to absorb more water molecules from the surface and thus increasing the rate of evaporation compared to hot, humid days where the air already has a high level of water vapor, slowing down evaporation. (b) Water boils at lower temperatures at higher altitudes due to decreased air pressure. To achieve the desired flavor extraction from tea leaves, boiling water at a lower temperature takes longer, resulting in longer boiling times at high altitudes compared to lower altitudes.

Step by step solution

01

(a) Explanation of evaporation on hot, dry and hot, humid days

Evaporation is the process where water molecules change their state from liquid to gas. This occurs when the water gains enough energy to overcome molecular bonds holding them together. It depends on multiple factors like temperature, humidity, and air pressure. On a hot day, the temperature is high, providing more energy to the water molecules to overcome molecular bonds, thus evaporating faster. The key difference between a hot, dry day and a hot, humid day is the degree of humidity. Humidity is the measure of moisture in the air. On hot, dry days, the air has lower humidity, meaning it has less water vapor in it. When there's less water vapor in the air, the air can absorb more water molecules from the surface, and the rate of evaporation increases. On hot, humid days, the air already has a high level of water vapor, which means it can absorb less water from the surface. This results in a slower rate of evaporation in comparison to a hot, dry day.
02

(b) Explanation of boiling water at high altitudes compared to lower altitudes

Boiling is the process where water reaches a temperature at which it starts converting from liquid to vapor. The boiling point of water depends on the surrounding air pressure. As altitude increases, air pressure decreases because there is less atmospheric pressure on the water from the weight of the air above it. At lower altitudes, air pressure is higher due to greater atmospheric pressure. This means that more energy is required to break the surface tension and allow water to evaporate. At higher altitudes, there is less air pressure, and therefore less energy is needed to break the surface tension. Due to this, water boils at lower temperatures at higher altitudes compared to lower altitudes. So, in order to make tea, the water needs to reach the desired boiling temperature for extraction of tea leaves' flavor and benefits. Boiling water at a lower temperature will take longer to extract the flavors, which means that it takes more time to reach the desired taste when boiling water at high altitudes compared to lower altitudes.

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Most popular questions from this chapter

Ethanol \(\left(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}\right)\) melts at \(-114^{\circ} \mathrm{C}\) and boils at \(78^{\circ} \mathrm{C}\). Its density is \(0.789 \mathrm{~g} / \mathrm{mL}\). The enthalpy of fusion of ethanol is \(5.02 \mathrm{~kJ} / \mathrm{mol}\), and its enthalpy of vaporization is \(38.56 \mathrm{~kJ} / \mathrm{mol}\). The specific heats of solid and liquid ethanol are \(0.97 \mathrm{~J} / \mathrm{g}-\mathrm{K}\) and \(2.3 \mathrm{~J} / \mathrm{g}-\mathrm{K}\), respectively. (a) How much heat is required to convert \(25.0 \mathrm{~g}\) of ethanol at \(25^{\circ} \mathrm{C}\) to the vapor phase at \(78^{\circ} \mathrm{C} ?\) (b) How much heat is required to convert \(5.00 \mathrm{~L}\) of ethanol at \(-140^{\circ} \mathrm{C}\) to the vapor phase at \(78^{\circ} \mathrm{C}\) ?

(a) What atoms must a molecule contain to participate in hydrogen bonding with other molecules of the same kind? (b) Which of the following molecules can form hydrogen bonds with other molecules of the same kind: \(\mathrm{CH}_{3} \mathrm{~F}, \mathrm{CH}_{3} \mathrm{NH}_{2}, \mathrm{CH}_{3} \mathrm{OH}, \mathrm{CH}_{3} \mathrm{Br} ?\)

The following quote about ammonia \(\left(\mathrm{NH}_{3}\right)\) is from a textbook of inorganic chemistry: "It is estimated that \(26 \%\) of the hydrogen bonding in \(\mathrm{NH}_{3}\) breaks down on melting, \(7 \%\) on warming from the melting to the boiling point, and the final \(67 \%\) on transfer to the gas phase at the boiling point." From the standpoint of the kinetic energy of the molecules, explain (a) why there is a decrease of hydrogen-bonding energy on melting and (b) why most of the loss in hydrogen bonding occurs in the transition from the liquid to the vapor state.

For each of the following pairs of substances, predict which will have the higher melting point and indicate why: (a) \(\mathrm{Ar}, \mathrm{Xe} ;\) (b) \(\mathrm{SiO}_{2}, \mathrm{CO}_{2} ;\) (c) \(\mathrm{KBr}, \mathrm{Br}_{2} ;\) (d) \(\mathrm{C}_{6} \mathrm{Cl}_{6}, \mathrm{C}_{6} \mathrm{H}_{6}\)

The critical temperatures (K) and pressures (atm) of a series of halogenated methanes are as follows: $$ \begin{array}{lllll} \hline \text { Compound } & \mathrm{CCl}_{3} \mathrm{~F} & \mathrm{CCl}_{2} \mathrm{~F}_{2} & \mathrm{CClF}_{3} & \mathrm{CF}_{4} \\ \hline \text { Critical Temperature } & 471 & 385 & 302 & 227 \\ \text { Critical Pressure } & 43.5 & 40.6 & 38.2 & 37.0 \\ \hline \end{array} $$ (a) List the intermolecular forces that occur for each compound. (b) Predict the order of increasing intermolecular attraction, from least to most, for this series of compounds. (c) Predict the critical temperature and pressure for \(\mathrm{CCl}_{4}\) based on the trends in this table. Look up the experimentally determined critical temperatures and pressures for \(\mathrm{CCl}_{4}\), using a source such as the \(\mathrm{CRC}\) Handbook of Chemistry and Physics, and suggest a reason for any discrepancies.

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