Chlorine dioxide gas \(\left(\mathrm{ClO}_{2}\right)\) is used as a commercial
bleaching agent. It bleaches materials by oxidizing them. In the course of
these reactions, the \(\mathrm{ClO}_{2}\) is itself reduced. (a) What is the
Lewis structure for \(\mathrm{ClO}_{2}\) ?
(b) Why do you think that \(\mathrm{ClO}_{2}\) is reduced so readily?
(c) When a \(\mathrm{ClO}_{2}\) molecule gains an electron, the chlorite ion,
\(\mathrm{ClO}_{2}^{-}\), forms. Draw the Lewis structure for
\(\mathrm{ClO}_{2}^{-}\).
(d) Predict the \(\mathrm{O}-\mathrm{Cl}-\mathrm{O}\) bond angle in the
\(\mathrm{ClO}_{2}^{-}\) ion.
(e) One method of preparing \(\mathrm{ClO}_{2}\) is by the reaction of chlorine
and sodium chlorite:
$$
\mathrm{Cl}_{2}(\mathrm{~g})+2 \mathrm{NaClO}_{2}(\mathrm{~s}) \longrightarrow
2 \mathrm{ClO}_{2}(\mathrm{~g})+2 \mathrm{NaCl}(\mathrm{s})
$$
If you allow \(10.0 \mathrm{~g}\) of \(\mathrm{NaClO}_{2}\) to react with \(2.00
\mathrm{~L}\) of chlorine gas at a pressure of \(1.50 \mathrm{~atm}\) at \(21{
}^{\circ} \mathrm{C}\), how many grams of \(\mathrm{ClO}_{2}\) can be prepared?