Question

Structural isomers. (a) Draw all of the isomers possible for \(\mathrm{C}_{3} \mathrm{H}_{8} \mathrm{O}\) Give the systematic name of each, and tell into which class of compound it fits. (b) Draw the structural formulas for an aldehyde and a ketone with the molecular formula \(\mathrm{C}_{4} \mathrm{H}_{8} \mathrm{O} .\) Give the systematic name of each.

Short answer

C3H8O: Propan-1-ol, Propan-2-ol, Methoxyethane; C4H8O: Butanal, Butan-2-one.

Step-by-step solution

Understanding the concept of isomers

Isomers are compounds with the same molecular formula but different structures. For C3H8O, the possible isomers include alcohols and ethers. For C4H8O, the compounds can be aldehydes or ketones.

Drawing structural isomers for C3H8O

For C3H8O, we can draw the following structural isomers:1. Propan-1-ol: \( \text{CH}_3\text{CH}_2\text{CH}_2\text{OH} \) - This is an alcohol.2. Propan-2-ol: \( \text{CH}_3\text{CH}(\text{OH})\text{CH}_3 \) - This is another alcohol.3. Methoxyethane: \( \text{CH}_3\text{CH}_2\text{OCH}_3 \) - This is an ether.

Assigning names and classes to C3H8O isomers

1. Propan-1-ol is a primary alcohol since the hydroxyl group is attached to the end of a carbon chain. 2. Propan-2-ol is a secondary alcohol as the hydroxyl group is attached to a middle carbon atom. 3. Methoxyethane is an ether due to the oxygen forming a bridge between two carbon chains.

Drawing structural formulas for C4H8O aldehyde

For C4H8O as an aldehyde, we have:- Butanal: \( \text{CH}_3\text{CH}_2\text{CH}_2\text{CHO} \). The aldehyde group (\(-CHO\)) is at the end of the carbon chain.

Drawing structural formulas for C4H8O ketone

For C4H8O as a ketone, we have:- Butan-2-one: \( \text{CH}_3\text{COCH}_2\text{CH}_3 \). The ketone group (\(-CO-\)) is between two carbon atoms but not at the end.

Assigning names to C4H8O aldehyde and ketone

1. Butanal is a straight-chain aldehyde. 2. Butan-2-one is a ketone with the carbonyl group in the second position of the chain.

Key concepts

Organic Chemistry

Organic chemistry is an essential branch of chemistry that studies carbon-containing compounds. These compounds can range from simple molecules like methane to large, complex structures like proteins and DNA.
Organic compounds are characterized by the presence of carbon atoms, often bonded to hydrogen, oxygen, nitrogen, and other elements. This field is crucial because many substances that are vital to life or industrial processes, such as fuels, plastics, drugs, and food, are made from organic compounds.
One interesting aspect of organic chemistry is the concept of structural isomers. These are compounds that have the same molecular formula but differ in their structural arrangement. For example, the molecule \\(\mathrm{C}_{3}\mathrm{H}_{8}\mathrm{O}\) has several structural isomers that fall into different classes like alcohols and ethers. Identifying these isomers is pivotal for the correct application and understanding of organic chemistry.

Functional Groups

Functional groups are specific groups of atoms within molecules that are responsible for the characteristic chemical reactions of those molecules. In organic chemistry, identifying the functional groups is crucial as it helps in predicting the behavior of the molecule in reactions.
Some common functional groups include:

• Hydroxyl group (-OH): Found in alcohols; e.g., propan-1-ol and propan-2-ol in the case of \\(\mathrm{C}_{3}\mathrm{H}_{8}\mathrm{O}\).
• Ether group (-O-): Characteristic of ethers, such as methoxyethane.
• Carbonyl group (-C=O): This group is present in aldehydes and ketones, specifically found in compounds like butanal and butan-2-one for \\(\mathrm{C}_{4}\mathrm{H}_{8}\mathrm{O}\).

Recognizing the functional group provides valuable insight into the chemical properties and reactions that these organic molecules can undergo. Understanding these groups helps learners make connections between structure and reactivity, a cornerstone in organic chemistry.

Systematic Nomenclature

Systematic nomenclature in organic chemistry offers a standardized way to name chemical compounds, making it easier for scientists around the world to communicate structure and function. It follows specific rules laid out by IUPAC (International Union of Pure and Applied Chemistry).
The methodology considers various factors:

• The length of the carbon chain: Base names like 'methane', 'ethane', 'propane', etc., correspond to the number of carbon atoms.
• The type and position of functional groups: For example, names like propan-1-ol and propan-2-ol denote where the hydroxyl group is situated.
• Special prefixes and suffixes: These describe the presence of specific functional groups; 'ol' for alcohols, 'al' for aldehydes, 'one' for ketones, etc.

The systematic naming of compounds like butanal and butan-2-one ensures precise communication about which compound is being referred to, based on its structure and functional groups. This system of nomenclature not only aids in efficient communication but also helps students and chemists predict the structure and reactions of different organic compounds.