Question

Identify the class of compounds that contains each of the following functional groups: a. a nitrogen atom attached to one or more carbon atoms b. a carboxyl group c. an oxygen atom bonded to two carbon atoms d. a carbonyl group between two carbon atoms

Short answer

a) Amines, b) Carboxylic acids, c) Ethers, d) Ketones.

Step-by-step solution

Determine the compound with a nitrogen atom attached to one or more carbon atoms

The functional group involving a nitrogen atom attached to one or more carbon atoms is characteristic of amines. Amines are classified based on the number of carbon atoms bonded to the nitrogen: primary (one carbon), secondary (two carbons), and tertiary (three carbons).

Identify the compound containing a carboxyl group

A carboxyl group consists of a carbon double-bonded to an oxygen (carbonyl) and singly bonded to a hydroxyl group (OH). Compounds containing the carboxyl group are known as carboxylic acids.

Recognize the compound with an oxygen atom bonded to two carbon atoms

The presence of an oxygen atom bonded to two carbon atoms identifies an ether. Ethers have the general formula R-O-R', where R and R' are carbon-containing groups.

Classify the compound with a carbonyl group between two carbon atoms

A carbonyl group (a carbon double-bonded to oxygen) situated between two carbon atoms characterizes a ketone. Ketones have the general formula R-CO-R', where R and R' are carbon-containing groups.

Key concepts

Amines

Amines are organic compounds that involve a nitrogen atom bonded to one or more carbon atoms. This nitrogen atom is what gives amines their distinct properties. They are classified based on the number of carbon atoms bonded to the nitrogen atom: primary amines have one carbon atom attached to the nitrogen, secondary amines have two carbon atoms, and tertiary amines have three carbon atoms. These classifications are important as they determine the reactivity and the types of reactions these amines can undergo.

Amines are basic (alkaline) compounds due to the lone pair of electrons on the nitrogen atom, which can accept protons (H+). This makes them useful in various chemical reactions, including acting as intermediates in the synthesis of pharmaceuticals, dyes, and other chemicals.

Carboxylic Acids

Carboxylic acids are organic compounds that possess a carboxyl group, which is composed of a carbon atom double-bonded to an oxygen atom (a carbonyl group) and singly bonded to a hydroxyl group (OH). The general formula for a carboxylic acid is R-COOH, where R represents a carbon-containing group.

Carboxylic acids are known for their acidic properties. They can donate a proton (H+) due to the highly polar nature of the bond between the oxygen and the hydrogen in the hydroxyl group. This makes carboxylic acids an important class of compounds in organic chemistry, with applications ranging from food preservatives (like acetic acid in vinegar) to the production of polymers (such as nylon). The acidity of carboxylic acids is also influenced by the nature of the R group, which can either enhance or reduce the acid's strength.

Ethers

Ethers are a type of organic compound characterized by an oxygen atom bonded to two carbon atoms. The general structure of an ether is R-O-R', where R and R' are carbon-containing groups, which can be either the same or different. Ethers are known for being relatively unreactive compared to other organic compounds, which makes them good solvents in chemical reactions.

The physical properties of ethers, such as their lower boiling points (compared to alcohols of similar molecular weight), are due to the absence of strong intermolecular hydrogen bonding. Ethers are widely used industrially, including as solvents and in the pharmaceutical industry. Their lack of reactivity in many conditions allows them to serve as a medium for other reactions without interfering.

Ketones

Ketones are characterized by the presence of a carbonyl group (C=O) bonded to two carbon atoms. The general formula for ketones is R-CO-R', where R and R' are carbon-containing groups. The carbonyl group in ketones contributes to their distinctive chemical properties.

Ketones are less reactive than aldehydes but more reactive than ethers. They typically participate in a variety of reactions, including nucleophilic addition and condensation reactions, making them a versatile functional group in organic chemistry. Ketones are commonly found in biological systems (e.g., as metabolic intermediates) and are also manufactured for use in solvents, such as acetone. Their unique structure and reactivity make them essential components in numerous chemical synthesis pathways.