Chapter 9: Problem 11
Why does water evaporate?
Chapter 9: Problem 11
Why does water evaporate?
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Get started for freeSuperalloys have been made of nickel and aluminum. The alloy owes its strength to the formation of an ordered phase, called the gamma-prime phase, in which Al atoms are at the corners of a cubic unit cell and Ni atoms are at the face centers. What is the composition (relative numbers of atoms) for this phase of the nickel-aluminum superalloy?
The memory metal, nitinol, is an alloy of nickel and titanium. It is called a memory metal because after being deformed, a piece of nitinol wire will return to its original shape. The structure of nitinol consists of a simple cubic array of Ni atoms and an inner penetrating simple cubic array of Ti atoms. In the extended lattice, a Ti atom is found at the center of a cube of Ni atoms; the reverse is also true. a. Describe the unit cell for nitinol. b. What is the empirical formula of nitinol? c. What are the coordination numbers (number of nearest neighbors) of Ni and Ti in nitinol?
The compounds \(\mathrm{Na}_{2} \mathrm{O},\) CdS, and \(\mathrm{ZrI}_{4}\) all can be described as cubic closest packed anions with the cations in tetrahedral holes. What fraction of the tetrahedral holes is occupied for each case?
The CsCl structure is a simple cubic array of chloride ions with a cesium ion at the center of each cubic array (see Exercise 69 ). Given that the density of cesium chloride is \(3.97 \mathrm{g} / \mathrm{cm}^{3},\) and assuming that the chloride and cesium ions touch along the body diagonal of the cubic unit cell, calculate the distance between the centers of adjacent \(\mathrm{Cs}^{+}\) and \(\mathrm{Cl}^{-}\) ions in the solid. Compare this value with the expected distance based on the sizes of the ions. The ionic radius of \(\mathrm{Cs}^{+}\) is \(169 \mathrm{pm},\) and the ionic radius of \(\mathrm{Cl}^{-}\) is \(181 \mathrm{pm}\).
The structure of manganese fluoride can be described as a simple cubic array of manganese ions with fluoride ions at the center of each edge of the cubic unit cell. What is the charge of the manganese ions in this compound?
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