Chapter 7: Problem 4
Liquid water turns to ice. Is this process endothermic or exothermic? Explain what is occurring using the terms system, surroundings, heat, potential energy, and kinetic energy in the discussion.
Chapter 7: Problem 4
Liquid water turns to ice. Is this process endothermic or exothermic? Explain what is occurring using the terms system, surroundings, heat, potential energy, and kinetic energy in the discussion.
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Get started for freeOne way to lose weight is to exercise! Walking briskly at 4.0 miles per hour for an hour consumes about 400 kcal of energy. How many hours would you have to walk at 4.0 miles per hour to lose one pound of body fat? One gram of body fat is equivalent to 7.7 kcal of energy. There are 454 g in 1 lb.
On Easter Sunday, April \(3,1983,\) nitric acid spilled from a tank car near downtown Denver, Colorado. The spill was neutralized with sodium carbonate: $$2 \mathrm{HNO}_{3}(a q)+\mathrm{Na}_{2} \mathrm{CO}_{3}(s) \longrightarrow 2 \mathrm{NaNO}_{3}(a q)+\mathrm{H}_{2} \mathrm{O}(l)+\mathrm{CO}_{2}(g)$$ a. Calculate \(\Delta H^{\circ}\) for this reaction. Approximately \(2.0 \times\) \(10^{4}\) gal nitric acid was spilled. Assume that the acid was an aqueous solution containing \(70.0 \%\) HNO \(_{3}\) by mass with a density of \(1.42 \mathrm{g} / \mathrm{cm}^{3} .\) What mass of sodium carbonate was required for complete neutralization of the spill, and what quantity of heat was evolved? \((\Delta H_{\mathrm{f}}^{\circ}\) for \(\mathrm{NaNO}_{3}(a q)=-467 \mathrm{kJ} / \mathrm{mol})\) b. According to The Denver Post for April \(4,1983,\) authorities feared that dangerous air pollution might occur during the neutralization. Considering the magnitude of \(\Delta H^{\circ}\) what was their major concern?
Consider the following statements: "Heat is a form of energy, and energy is conserved. The heat lost by a system must be equal to the amount of heat gained by the surroundings. Therefore, heat is conserved." Indicate everything you think is correct in these statements. Indicate everything you think is incorrect. Correct the incorrect statements and explain.
For the reaction \(\mathrm{HgO}(s) \rightarrow \mathrm{Hg}(l)+\frac{1}{2} \mathrm{O}_{2}(g), \Delta H=+90.7 \mathrm{kJ}\). a. What quantity of heat is required to produce 1 mole of mercury by this reaction? b. What quantity of heat is required to produce 1 mole of oxygen gas by this reaction? c. What quantity of heat would be released in the following reaction as written? $$2 \mathrm{Hg}(l)+\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{HgO}(s)$$
Explain why oceanfront areas generally have smaller temperature fluctuations than inland areas.
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