Chapter 7: Problem 2
What is meant by the term lower in energy? Which is lower in energy, a mixture of hydrogen and oxygen gases or liquid water? How do you know? Which of the two is more stable? How do you know?
Chapter 7: Problem 2
What is meant by the term lower in energy? Which is lower in energy, a mixture of hydrogen and oxygen gases or liquid water? How do you know? Which of the two is more stable? How do you know?
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Get started for freeOne mole of \(\mathrm{H}_{2} \mathrm{O}(g)\) at 1.00 atm and \(100 .^{\circ} \mathrm{C}\) occupies a volume of 30.6 L. When 1 mole of \(\mathrm{H}_{2} \mathrm{O}(g)\) is condensed to 1 mole of \(\mathrm{H}_{2} \mathrm{O}(l)\) at 1.00 atm and \(100 .^{\circ} \mathrm{C}, 40.66 \mathrm{kJ}\) of heat is released. If the density of \(\mathrm{H}_{2} \mathrm{O}(l)\) at this temperature and pressure is \(0.996 \mathrm{g} / \mathrm{cm}^{3},\) calculate \(\Delta E\) for the condensation of 1 mole of water at 1.00 atm and \(100 .^{\circ} \mathrm{C}\).
Hess's law is really just another statement of the first law of thermodynamics. Explain.
Which of the following processes are exothermic? a. \(\mathrm{N}_{2}(g) \longrightarrow 2 \mathrm{N}(g)\) b. \(\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{H}_{2} \mathrm{O}(s)\) c. \(\mathrm{Cl}_{2}(g) \longrightarrow 2 \mathrm{Cl}(g)\) d. \(2 \mathrm{H}_{2}(g)+\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{H}_{2} \mathrm{O}(g)\) e. \(\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{O}(g)\)
The enthalpy of combustion of solid carbon to form carbon dioxide is \(-393.7 \mathrm{kJ} / \mathrm{mol}\) carbon, and the enthalpy of combustion of carbon monoxide to form carbon dioxide is \(-283.3 \mathrm{kJ} / \mathrm{mol}\) CO. Use these data to calculate \(\Delta H\) for the reaction $$2 \mathrm{C}(s)+\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{CO}(g)$$
The standard enthalpy of combustion of ethene gas, \(\mathrm{C}_{2} \mathrm{H}_{4}(g)\) is \(-1411.1 \mathrm{kJ} / \mathrm{mol}\) at \(298 \mathrm{K}\). Given the following enthalpies of formation, calculate \(\Delta H_{\mathrm{f}}^{\circ}\) for \(\mathrm{C}_{2} \mathrm{H}_{4}(g)\). $$\begin{array}{ll}\mathrm{CO}_{2}(g) & -393.5 \mathrm{kJ} / \mathrm{mol} \\\\\mathrm{H}_{2} \mathrm{O}(l) & -285.8 \mathrm{kJ} / \mathrm{mol}\end{array}$$
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