Chapter 21: Problem 24
Draw the structures for two examples of unsaturated hydrocarbons. What structural feature makes a hydrocarbon unsaturated?
Chapter 21: Problem 24
Draw the structures for two examples of unsaturated hydrocarbons. What structural feature makes a hydrocarbon unsaturated?
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Get started for freeDraw the structure for 4-ethyl-2,3-diisopropylpentane. This name is incorrect. Give the correct systematic name.
Mimosine is a natural product found in large quantities in the seeds and foliage of some legume plants and has been shown to cause inhibition of hair growth and hair loss in mice. a. What functional groups are present in mimosine? b. Give the hybridization of the eight carbon atoms in mimosine. c. How many \(\sigma\) and \(\pi\) bonds are found in mimosine?
Is octanoic acid more soluble in \(1 \mathrm{M} \mathrm{HCl}, 1 M \mathrm{NaOH},\) or pure water? Explain. Drugs such as morphine \(\left(\mathrm{C}_{17} \mathrm{H}_{19} \mathrm{NO}_{3}\right)\) are often treated with strong acids. The most commonly used form of morphine is morphine hydrochloride \(\left(\mathrm{C}_{1} \mathrm{H}_{20} \mathrm{ClNO}_{3}\right) .\) Why is morphine treated in this way? (Hint: Morphine is an amine.)
In glycine, the carboxylic acid group has \(K_{\mathrm{a}}=4.3 \times 10^{-3}\) and the amino group has \(K_{b}=6.0 \times 10^{-5} .\) Use these equilibrium constant values to calculate the cquilibrium constants for the following. a. \(^{+} \mathrm{H}_{3} \mathrm{NCH}_{2} \mathrm{CO}_{2}^{-}+\mathrm{H}_{2} \mathrm{O} \rightleftharpoons \mathrm{H}_{2} \mathrm{NCH}_{2} \mathrm{CO}_{2}^{-}+\mathrm{H}_{3} \mathrm{O}^{+}\) b. \(\mathrm{H}_{2} \mathrm{NCH}_{2} \mathrm{CO}_{2}^{-}+\mathrm{H}_{2} \mathrm{O} \rightleftharpoons \mathrm{H}_{2} \mathrm{NCH}_{2} \mathrm{CO}_{2} \mathrm{H}+\mathrm{OH}^{-}\) c. \(\mathbf{H}_{3} \mathrm{NCH}_{2} \mathrm{CO}_{2} \mathrm{H} \rightleftharpoons 2 \mathrm{H}^{+}+\mathrm{H}_{2} \mathrm{NCH}_{2} \mathrm{CO}_{2}^{-}\)
Draw cyclic structures for D-ribose and D-mannose.
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