Chapter 20: Problem 38
Give formulas for the following complex ions. a. tetrachloroferrate(III) ion b. pentaammineaquaruthenium(III) ion c. tetracarbonyldihydroxochromium(III) ion d. amminetrichloroplatinate(II) ion
Chapter 20: Problem 38
Give formulas for the following complex ions. a. tetrachloroferrate(III) ion b. pentaammineaquaruthenium(III) ion c. tetracarbonyldihydroxochromium(III) ion d. amminetrichloroplatinate(II) ion
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Get started for freeOne of the classic methods for the determination of the manganese content in steel involves converting all the manganese to the deeply colored permanganate ion and then measuring the absorption of light. The steel is first dissolved in nitric acid, producing the manganese(II) ion and nitrogen dioxide gas. This solution is then reacted with an acidic solution containing periodate ion; the products are the permanganate and iodate ions. Write balanced chemical equations for both of these steps.
A metal ion in a high-spin octahedral complex has two more unpaired electrons than the same ion does in a low-spin octahedral complex. Name some possible metal ions for which this would be true.
Would it be better to use octahedral \(\mathrm{Ni}^{2+}\) complexes or octahedral \(\mathrm{Cr}^{2+}\) complexes to determine whether a given ligand is a strong-field or weak-field ligand by measuring the number of unpaired electrons? How else could the relative ligand field strengths be determined?
Consider the complex ions \(\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}^{3+}, \mathrm{Co}(\mathrm{CN})_{6}^{3-},\) and \(\mathrm{CoF}_{6}^{3-} .\) The wavelengths of absorbed electromagnetic radiation for these compounds (in no specific order) are \(770 \mathrm{nm}\) \(440 \mathrm{nm},\) and \(290 \mathrm{nm} .\) Match the complex ion to the wavelength of absorbed electromagnetic radiation.
Consider the pseudo-octahedral complex ion of \(\mathrm{Cr}^{3+},\) where \(\mathrm{A}\) and B represent ligands. Ligand A produces a stronger crystal field than ligand B. Draw an appropriate crystal field diagram for this complex ion (assume the A ligands are on the \(z\) -axis).
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