Chapter 2: Problem 81
Give the maximum number of electrons in an atom that can have these quantum
numbers:
a.
Short Answer
Expert verified
a. Maximum number of electrons: 32
b. Maximum number of electrons: 4
c. Maximum number of electrons: 25
d. Maximum number of electrons: 10
e. Maximum number of electrons: 6
Step by step solution
01
Find the possible values of _ell
Since the principal quantum number n=4, the possible values of _ell are 0, 1, 2, and 3.
02
Find the possible values of m_ell for each _ell
For each value of _ell, the possible values of m_ell are as follows:
- _ell = 0: m_ell = 0
- _ell = 1: m_ell = -1, 0, +1
- _ell = 2: m_ell = -2, -1, 0, +1, +2
- _ell = 3: m_ell = -3, -2, -1, 0, +1, +2, +3
03
Find the total number of electrons
For each value of m_ell, there are two possible values of m_s. Thus we have:
- _ell = 0: 2 electrons
- _ell = 1: 6 electrons
- _ell = 2: 10 electrons
- _ell = 3: 14 electrons
So, for n=4, the total number of electrons is .
#a. Maximum number of electrons: 32#
#b. n=5, m_ell=+1#
04
Find the possible values of _ell for m_ell=+1
Possible values of _ell for m_ell=+1 are _ell=1 and _ell=2.
05
Find the total number of electrons for each _ell
For each value of m_ell, there are two possible values of m_s:
- _ell = 1: 2 electrons
- _ell = 2: 2 electrons
So, for n=5 and m_ell=+1, the total number of electrons is .
#b. Maximum number of electrons: 4#
#c. n=5, m_s=+1/2#
06
Calculate possible values of _ell and m_ell
For n=5, possible values of _ell are 0, 1, 2, 3, 4, and for each _ell, we can have their respective m_ell values.
07
Find the total number of electrons
For all of these cases, m_s=+1/2, so there will be only 1 electron for each of m_ell.
Counting the possible combinations, we have a total of: 1 + 3 + 5 + 7 +9 = 25 electrons.
#c. Maximum number of electrons: 25#
#d. n=3, _ell=2#
08
Determine the possible values of m_ell
For _ell=2, the possible values of m_ell are: -2, -1, 0, +1, +2.
09
Find the total number of electrons
For each value of m_ell, there are two possible values of m_s. Thus we have 5 × 2 = 10 electrons.
#d. Maximum number of electrons: 10#
#e. n=2, _ell=1#
10
Determine the possible values of m_ell
For _ell=1, the possible values of m_ell are: -1, 0, +1.
11
Find the total number of electrons
For each value of m_ell, there are two possible values of m_s. Thus we have 3 × 2 = 6 electrons.
#e. Maximum number of electrons: 6#
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