Chapter 19: Problem 2
List two major industrial uses of hydrogen.
Chapter 19: Problem 2
List two major industrial uses of hydrogen.
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Get started for freeLead forms compounds in the +2 and +4 oxidation states. All lead(II) halides are known (and are known to be ionic). Only \(\mathrm{PbF}_{4}\) and \(\mathrm{PbCl}_{4}\) are known among the possible lead(IV) halides. Presumably lead(IV) oxidizes bromide and iodide ions, producing the lead(II) halide and the free halogen:$$\mathrm{PbX}_{4} \longrightarrow\mathrm{PbX}_{2}+\mathrm{X}_{2}$$. Suppose \(25.00 \mathrm{g}\) of a lead(IV) halide reacts to form \(16.12 \mathrm{g}\) of a lead(II) halide and the free halogen. Identify the halogen.
EDTA is used as a complexing agent in chemical analysis. Solutions of EDTA, usually containing the disodium salt \(\mathrm{Na}_{2} \mathrm{H}_{2} \mathrm{EDTA},\) are also used to treat heavy metal poisoning. The equilibrium constant for the following reaction is \(6.7 \times 10^{21}\) Calculate \(\left[\mathrm{Pb}^{2+}\right]\) at equilibrium in a solution originally \(0.0050 M\) in \(\mathrm{Pb}^{2+}, 0.075 M\) in \(\mathrm{H}_{2} \mathrm{EDTA}^{2-},\) and buffered at \(\mathrm{pH}=7.00\):.
In each of the following pairs of substances, one is stable and known, and the other is unstable. For each pair, choose the stable substance, and explain why the other is unstable. a. \(\mathrm{NF}_{5}\) or \(\mathrm{PF}_{5}\) b. \(\mathrm{AsF}_{5}\) or \(\mathrm{AsI}_{5}\) c. \(\mathrm{NF}_{3}\) or \(\mathrm{NBr}_{3}\)
Complete and balance each of the following reactions. a. the reaction between sulfur dioxide gas and oxygen gas b. the reaction between sulfur trioxide gas and water c. the reaction between concentrated sulfuric acid and su\(\operatorname{crose}\left(\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}\right)\)
Describe the bonding in \(\mathrm{SO}_{2}\) and \(\mathrm{SO}_{3}\) using the localized electron model (hybrid orbital theory). How would the molecular orbital model describe the \(\pi\) bonding in these two compounds?
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