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The easiest fusion reaction to initiate is $$\frac{2}{1} \mathrm{H}+\frac{3}{1} \mathrm{H} \longrightarrow_{2}^{4} \mathrm{He}+\frac{1}{0} \mathrm{n}$$ Calculate the energy released per \(\frac{4}{2} \mathrm{He}\) nucleus produced and per mole of \(^{4}_{2}\) He produced. The atomic masses are \(\frac{2}{1} \mathrm{H}\) \(2.01410 \mathrm{u} ; \frac{3}{1} \mathrm{H}, 3.01605 \mathrm{u} ;\) and \(\frac{4}{2} \mathrm{He}, 4.00260 \mathrm{u} .\) The masses of the electron and neutron are \(5.4858 \times 10^{-4} \mathrm{u}\) and \(1.00866 \mathrm{u}\) respectively.

Short Answer

Expert verified
mass loss = 5.03015 u - 5.01126 u mass loss = 0.01889 u #tag_title#Calculate the energy released per Helium-4 nucleus#tag_content# To calculate the energy released, we will use the mass-energy equivalence formula: \(E = mc^2\), where \(E\) is the energy, \(m\) is the mass, and \(c\) is the speed of light in a vacuum. We will convert the mass loss from atomic units (u) to kilograms (kg) using the conversion factor: 1 u = 1.66054 × 10^{-27} kg. The speed of light is approximately 3 × 10^8 m/s. Energy = (0.01889 u) (1.66054 × 10^{-27} kg/u) (3 × 10^8 m/s)^2 Energy ≈ 1.6904 × 10^{-12} J #tag_title#Calculate the energy released per mole of Helium-4#tag_content# Now that we have the energy released per Helium-4 nucleus, we can calculate the energy released per mole of Helium-4. Since there are \(6.022 \times 10^{23}\) particles in one mole, we simply multiply the energy per nucleus by Avogadro's number to obtain the energy per mole. Energy per mole = (1.6904 × 10^{-12} J/nucleus) (6.022 × 10^23 nuclei/mole) Energy per mole ≈ 1.017 × 10^12 J/mole Thus, the energy released per Helium-4 nucleus produced is approximately \(1.6904 \times 10^{-12}\) joules, and the energy released per mole of Helium-4 produced is approximately \(1.017 \times 10^{12}\) joules.

Step by step solution

01

Calculate the mass loss in the reaction

First, we need to find the mass change between the initial reactants and the final products. The mass change can be calculated as follows: mass loss = (mass of reactants) - (mass of products) The mass of reactants includes one deuterium atom and one tritium atom. The mass of products includes one helium-4 atom and one neutron. mass loss = (mass of deuterium + mass of tritium) - (mass of helium-4 + mass of neutron) Using the provided atomic masses, we can plug in the values: mass loss = (2.01410 u + 3.01605 u) - (4.00260 u + 1.00866 u)

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Energy Release Calculation
In nuclear fusion, calculating the energy released during a reaction is essential for understanding its power output. To determine this, we first calculate the mass lost in the fusion process. This loss results from the conversion of the reactants' mass into energy, in line with Einstein's theory of relativity.

For the reaction \(^{2}_1\mathrm{H} + ^{3}_1\mathrm{H} \rightarrow ^{4}_2\mathrm{He} + ^{1}_0\mathrm{n}\), the energy release comes from the mass difference (mass defect) between the initial reactants and the final products.

  • Mass of Reactants: Deuterium (\(^{2}_1\mathrm{H}\)) and Tritium (\(^{3}_1\mathrm{H}\))
  • Mass of Products: Helium-4 (\(^{4}_2\mathrm{He}\)) and a neutron (\(^{1}_0\mathrm{n}\))
The energy released can be calculated with the mass-energy equivalence formula, that relates mass loss to energy.
Mass-Energy Equivalence
Einstein's famous equation \(E=mc^2\) forms the foundation for understanding how mass is converted into energy in nuclear reactions. In this formula, \(E\) is the energy produced, \(m\) is the mass defect that occurs during the reaction, and \(c\) is the speed of light in a vacuum (\(c = 3 \, \times\ 10^8 \, \mathrm{m/s}\)).

This equation implies that the conversion of even a small amount of mass can yield a significant amount of energy, due to the speed of light being such a large number:

  • Fusion reactions show this principle clearly—where the small atomic mass units lost are transformed into substantial energy outputs.
  • The energy released in nuclear fusion is significantly more per unit mass than chemical reactions, such as burning coal or gasoline.
Understanding mass-energy equivalence is crucial to grasp why nuclear fusion is a potent source of energy.
Atomic Mass Units
The atomic mass unit (u) is a standard unit of mass that quantifies the mass of atomic and subatomic particles. It is defined as one-twelfth of the mass of a carbon-12 atom. This unit is crucial when calculating mass differences in nuclear reactions.

For example, in our reaction:

  • Deuterium (\(^{2}_1\mathrm{H}\)): 2.01410 u
  • Tritium (\(^{3}_1\mathrm{H}\)): 3.01605 u
  • Helium-4 (\(^{4}_2\mathrm{He}\)): 4.00260 u
  • Neutron (\(^{1}_0\mathrm{n}\)): 1.00866 u
The precision of atomic mass values allows for accurate measurements of the mass defect, essential for calculating energy release in nuclear reactions.

The atomic mass unit simplifies the complex calculations of nuclear chemistry, translating minute mass differences into significant energy outputs.
Nuclear Reactions
Nuclear reactions involve changes in an atom's nucleus and typically require or release large amounts of energy. Here, two light nuclei combine to form a heavier nucleus, releasing energy in the process.

Fusion reactions, such as the deuterium-tritium reaction discussed here, are a prime example. These reactions aim to replicate the processes occurring in stars, where immense pressure and temperature allow for continuous nuclear fusion.

Key characteristics of nuclear reactions include:

  • Involvement of nuclear forces, which are much stronger than chemical forces acting between atoms.
  • Energy changes that are significantly larger than in typical chemical reactions.
  • Products of fusion reactions are often stable or emit less radioactive material, compared to other types of nuclear reactions, such as fission.
Understanding nuclear fusion reactions is fundamental to advancing nuclear energy technology and potentially solving global energy challenges.

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Most popular questions from this chapter

The mass ratios of \(^{40} \mathrm{Ar}\) to \(^{40} \mathrm{K}\) also can be used to date geologic materials. Potassium-40 decays by two processes: $$\begin{aligned} &_{19}^{40} \mathrm{K}+_{-1}^{0} \mathrm{e} \longrightarrow_{18}^{40} \mathrm{Ar}(10.7 \%) \quad t_{1 / 2}=1.27 \times 10^{9} \text { years }\\\ &_{19}^{40} \mathrm{K} \longrightarrow_{20}^{40} \mathrm{Ca}+_{-1}^{0} \mathrm{e}(89.3 \%) \end{aligned}$$a. Why are \(^{40} \mathrm{Ar} /^{40} \mathrm{K}\) ratios used to date materials rather than \(^{40} \mathrm{Ca} /^{40} \mathrm{K}\) ratios? b. What assumptions must be made using this technique? c. A sedimentary rock has an \(^{40} \mathrm{Ar} /^{40} \mathrm{K}\) ratio of 0.95. Calculate the age of the rock. d. How will the measured age of a rock compare to the actual age if some \(^{40}\) Ar escaped from the sample?

Uranium- 235 undergoes many different fission reactions. For one such reaction, when \(^{235} \mathrm{U}\) is struck with a neutron, \(^{144} \mathrm{Ce}\) and \(^{90}\) Sr are produced along with some neutrons and electrons. How many neutrons and \(\beta\) -particles are produced in this fission reaction?

Breeder reactors are used to convert the nonfissionable nuclide \(\frac{238}{92} \mathrm{U}\) to a fissionable product. Neutron capture of the \(\frac{238}{92} \mathrm{U}\) is followed by two successive beta decays. What is the final fissionable product?

At a flea market, you've found a very interesting painting done in the style of Rembrandt's "dark period" (1642-1672). You suspect that you really do not have a genuine Rembrandt, but you take it to the local university for testing. Living wood shows a carbon- 14 activity of 15.3 counts per minute per gram. Your painting showed a carbon- 14 activity of 15.1 counts per minute per gram. Could it be a genuine Rembrandt?

Zirconium is one of the few metals that retains its structural integrity upon exposure to radiation. The fuel rods in most nuclear reactors therefore are often made of zirconium. Answer the following questions about the redox properties of zirconium based on the half-reaction $$\mathrm{ZrO}_{2} \cdot \mathrm{H}_{2} \mathrm{O}+\mathrm{H}_{2} \mathrm{O}+4 \mathrm{e}^{-} \longrightarrow \mathrm{Zr}+4 \mathrm{OH}^{-} \quad \mathscr{C}^{\circ}=-2.36 \mathrm{V}$$a. Is zirconium metal capable of reducing water to form hydrogen gas at standard conditions? b. Write a balanced equation for the reduction of water by zirconium. c. Calculate \(\mathscr{E}^{\circ}, \Delta G^{\circ},\) and \(K\) for the reduction of water by zirconium metal. d. The reduction of water by zirconium occurred during the accidents at Three Mile Island in \(1979 .\) The hydrogen produced was successfully vented and no chemical explosion occurred. If \(1.00 \times 10^{3} \mathrm{kg}\) Zr reacts, what mass of \(\mathrm{H}_{2}\) is produced? What volume of \(\mathrm{H}_{2}\) at 1.0 atm and \(1000 .^{\circ} \mathrm{C}\) is produced? e. At Chernobyl in \(1986,\) hydrogen was produced by the reaction of superheated steam with the graphite reactor core:$$\mathbf{C}(s)+\mathbf{H}_{2} \mathbf{O}(g) \longrightarrow \mathbf{C O}(g)+\mathbf{H}_{2}(g)$$ It was not possible to prevent a chemical explosion at Chernobyl. In light of this, do you think it was a correct decision to vent the hydrogen and other radioactive gases into the atmosphere at Three Mile Island? Explain.

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