Chapter 11: Problem 19
The central idea of the collision model is that molecules must collide in order to react. Give two reasons why not all collisions of reactant molecules result in product formation.
Chapter 11: Problem 19
The central idea of the collision model is that molecules must collide in order to react. Give two reasons why not all collisions of reactant molecules result in product formation.
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Get started for freeEach of the statements given below is false. Explain why. a. The activation energy of a reaction depends on the overall energy change \((\Delta E)\) for the reaction. b. The rate law for a reaction can be deduced from examination of the overall balanced equation for the reaction. c. Most reactions occur by one-step mechanisms.
One reason suggested for the instability of long chains of silicon atoms is that the decomposition involves the transition state shown below: The activation energy for such a process is \(210 \space\mathrm{kJ} / \mathrm{mol}\), which is less than either the \(\mathrm{Si}-\mathrm{Si}\) or the \(\mathrm{Si}-\mathrm{H}\) bond energy. Why would a similar mechanism not be expected to play a very important role in the decomposition of long chains of carbon atoms as seen in organic compounds?
Consider two reaction vessels, one containing A and the other containing \(\mathrm{B},\) with equal concentrations at \(t=0 .\) If both substances decompose by first-order kinetics, where $$\begin{aligned} &k_{A}=4.50 \times 10^{-4} \mathrm{s}^{-1}\\\ &k_{\mathrm{B}}=3.70 \times 10^{-3} \mathrm{s}^{-1} \end{aligned}$$how much time must pass to reach a condition such that \([\mathrm{A}]=\) \(4.00[\mathrm{B}] ?\)
The activation energy for the reaction $$\mathrm{NO}_{2}(g)+\mathrm{CO}(g) \longrightarrow \mathrm{NO}(g)+\mathrm{CO}_{2}(g)$$ is \(125 \mathrm{kJ} / \mathrm{mol},\) and \(\Delta E\) for the reaction is \(-216 \mathrm{kJ} / \mathrm{mol}\). What is the activation energy for the reverse reaction \(\left[\mathrm{NO}(g)+\mathrm{CO}_{2}(g) \longrightarrow \mathrm{NO}_{2}(g)+\mathrm{CO}(g)\right] ?\)
Upon dissolving \(\operatorname{InCl}(s)\) in \(\mathrm{HCl}, \operatorname{In}^{+}(a q)\) undergoes a disproportionation reaction according to the following unbalanced equation: $$\operatorname{In}^{+}(a q) \longrightarrow \operatorname{In}(s)+\operatorname{In}^{3+}(a q)$$ This disproportionation follows first-order kinetics with a half-life of 667 s. What is the concentration of \(\operatorname{In}^{+}(a q)\) after \(1.25 \mathrm{h}\) if the initial solution of \(\operatorname{In}^{+}(a q)\) was prepared by dissolving \(2.38 \mathrm{g}\) InCl \((s)\) in dilute HCl to make \(5.00 \times 10^{2} \mathrm{mL}\) of solution? What mass of \(\operatorname{In}(s)\) is formed after \(1.25 \mathrm{h} ?\)
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